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• W2966547 abstract "The influence of particle size, crystallite size, and lattice defects on hydrogen storage capacity and absorption–desorption kinetics of nanostructured materials are overviewed. It is shown that the particle and crystallite sizes and catalyst play two different roles in the sorption process. By decreasing the particle and crystallite sizes, the required diffusion path of hydrogen is drastically reduced that enhances the sorption kinetics significantly. At the same time, catalysts have a promoting effect on dissociation or recombination of hydrogen molecules on the particles' surfaces, and they also act as chemisorption sites. The lattice defects (dislocations, stacking faults, and twin boundaries) facilitate the diffusion of hydrogen and the nucleation of hydride phases. It is revealed that large amounts of dislocations and/or planar faults are formed due to stresses induced by phase transformations in hydrogenation and dehydrogenation processes. The effect of defects on hydrogen storage capacity of carbon nanotubes is also reviewed." @default.
• W2966547 created "2016-06-24" @default.
• W2966547 creator A5067866773 @default.
• W2966547 date "2017-01-01" @default.
• W2966547 modified "2023-10-11" @default.
• W2966547 title "Relationship Between Microstructure and Hydrogen Storage Properties of Nanomaterials" @default.
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• W2966547 doi "https://doi.org/10.1016/b978-0-08-101917-7.00011-6" @default.
• W2966547 hasPublicationYear "2017" @default.
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