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- W2966804906 abstract "A catalyst-controlled regiodivergent and stereospecific ring-opening C(sp3)-Si cross-coupling of 2-arylaziridines with silylborane enabled by synergistic Pd/Cu dual catalysis has been developed. Just by selecting a suitable combination of catalysts, the regioselectivity of the coupling is completely switched to efficiently provide two regioisomers of β-silylamines (i.e., β-silyl-α-phenethylamines and β-silyl-β-phenethylamines) in good to high yields. Furthermore, a slight modification of the reaction conditions caused a drastic change in reaction pathways, leading to a tandem reaction to produce another regioisomer of silylamine (i.e., α-silyl-β-phenethylamines) in an efficient and selective manner." @default.
- W2966804906 created "2019-08-13" @default.
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- W2966804906 date "2019-01-01" @default.
- W2966804906 modified "2023-10-05" @default.
- W2966804906 title "Catalyst-controlled regiodivergent ring-opening C(sp<sup>3</sup>)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis" @default.
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- W2966804906 doi "https://doi.org/10.1039/c9sc02507c" @default.
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