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- W2967193798 abstract "$mathrm{Zn}{M}_{2}^{III}{mathrm{O}}_{4}$ (${M}^{III}=text{Co}$, Rh, Ir) spinels have been recently identified as promising $p$-type semiconductors for transparent electronics. However, discrepancies exist in the literature regarding their fundamental optoelectronic properties. In this paper, the electronic structures of these spinels are directly investigated using soft/hard x-ray photoelectron and x-ray absorption spectroscopies in conjunction with density functional theory calculations. In contrast to previous results, ${mathrm{ZnCo}}_{2}{mathrm{O}}_{4}$ is found to have a small electronic band gap with forbidden optical transitions between the true band edges, allowing for both bipolar doping and high optical transparency. Furthermore, increased $densuremath{-}d$ splitting combined with a concomitant lowering of Zn $s/p$ conduction states is found to result in a ${mathrm{ZnCo}}_{2}{mathrm{O}}_{4}phantom{rule{0.28em}{0ex}}(text{ZCO})<{mathrm{ZnRh}}_{2}{mathrm{O}}_{4}phantom{rule{0.28em}{0ex}}(text{ZRO})ensuremath{approx}{mathrm{ZnIr}}_{2}{mathrm{O}}_{4}phantom{rule{0.28em}{0ex}}(text{ZIO})$ band gap trend, finally resolving long-standing discrepancies in the literature." @default.
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- W2967193798 date "2019-08-15" @default.
- W2967193798 modified "2023-10-09" @default.
- W2967193798 title "Band edge evolution of transparent <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>Zn</mml:mi><mml:msubsup><mml:mi>M</mml:mi><mml:mn>2</mml:mn><mml:mrow><mml:mi>I</mml:mi><mml:mi>I</mml:mi><mml:mi>I</mml:mi></mml:mrow></mml:msubsup><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math> ( <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msup><mml:mi>M</mml:mi><mml:mrow><mml:mi>I</mml:mi><mml:mi>I</mml…" @default.
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- W2967193798 doi "https://doi.org/10.1103/physrevb.100.085126" @default.
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