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• W2967351487 endingPage "25038" @default.
• W2967351487 startingPage "25034" @default.
• W2967351487 abstract "Polysubstituted furans were prepared in moderate to good yields from various sulfur ylides and alkyl acetylenic carboxylates. The direct reactions of dimethylsulfonium acylmethylides with dialkyl acetylenedicarboxylates afforded dialkyl furan-3,4-dicarboxylates through a tandem sequence of Michael addition, intramolecular nucleophilic addition, 4π ring opening, intramolecular Michael addition, and elimination. The method was extended to synthesize furan-3-carboxylate, -2,4-dicarboxylates, and -2,3,4-tricarboxylates as well. The current method provides a direct and simple strategy in the synthesis of structurally diverse polysubstituted furans with mono to tricarboxylate groups from safe and readily available dimethylsulfonium acylmethylides and different alkyl acetylenic carboxylates." @default.
• W2967351487 created "2019-08-22" @default.
• W2967351487 creator A5029017134 @default.
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• W2967351487 date "2019-01-01" @default.
• W2967351487 modified "2023-10-18" @default.
• W2967351487 title "Regiospecific synthesis of polysubstituted furans with mono- to tricarboxylates from various sulfonium acylmethylides and acetylenic esters" @default.
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• W2967351487 doi "https://doi.org/10.1039/c9ra03563j" @default.
• W2967351487 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35528645" @default.
• W2967351487 hasPublicationYear "2019" @default.
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