FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2967398788> ?p ?o ?g. }

• W2967398788 endingPage "4104" @default.
• W2967398788 startingPage "4093" @default.
• W2967398788 abstract "A new PCcarbeneS ligand has been designed to stabilize late transition metal carbene complexes with Schrock-type reactivity for bond activations via metal–ligand cooperation. This ligand combines previous approaches to such complexes by stabilizing the carbene moiety through either charge delocalization into adjacent aryl groups or the use of an anion-stabilizing substituent. Nickel and palladium complexes of the PCcarbeneS pincer ligand could be prepared by dehydrohalogenation of the precursors (PCsp3S)NiCl and (PCsp3S)PdCl and were characterized in solution and solid state. X-ray diffraction (XRD) analyses as well as density functional theory (DFT) studies demonstrate that the electronic structure of these complexes can be described by a carbene as well as a zwitterionic complex with a M–C single bond. Due to the strong nucleophilic character at the carbon atom, both complexes are highly reactive and undergo sulfur transfer to form thioketone complexes. The nickel carbene complex is capable of cooperative O–H and N–H bond activations including ammonia activation across the Ni═C bond." @default.
• W2967398788 created "2019-08-22" @default.
• W2967398788 creator A5013631067 @default.
• W2967398788 creator A5029673914 @default.
• W2967398788 creator A5044074956 @default.
• W2967398788 creator A5053558508 @default.
• W2967398788 creator A5054638656 @default.
• W2967398788 date "2019-08-12" @default.
• W2967398788 modified "2023-10-10" @default.
• W2967398788 title "Cooperative Bond Activation Reactions with Nickel and Palladium Carbene Complexes with a PC_carbeneS Pincer Ligand" @default.
• W2967398788 cites W1873972401 @default.
• W2967398788 cites W1964837435 @default.
• W2967398788 cites W1966182479 @default.
• W2967398788 cites W1968490038 @default.
• W2967398788 cites W1969360633 @default.
• W2967398788 cites W1974945095 @default.
• W2967398788 cites W1980275197 @default.
• W2967398788 cites W1986466156 @default.
• W2967398788 cites W1988091937 @default.
• W2967398788 cites W2007302041 @default.
• W2967398788 cites W2008423326 @default.
• W2967398788 cites W2009236200 @default.
• W2967398788 cites W2016132894 @default.
• W2967398788 cites W2019864853 @default.
• W2967398788 cites W2020983009 @default.
• W2967398788 cites W2021231925 @default.
• W2967398788 cites W2030976617 @default.
• W2967398788 cites W2034798566 @default.
• W2967398788 cites W2037906407 @default.
• W2967398788 cites W2038767330 @default.
• W2967398788 cites W2042253155 @default.
• W2967398788 cites W2044490585 @default.
• W2967398788 cites W2061429138 @default.
• W2967398788 cites W2066721851 @default.
• W2967398788 cites W2068617439 @default.
• W2967398788 cites W2076320031 @default.
• W2967398788 cites W2076937017 @default.
• W2967398788 cites W2077729746 @default.
• W2967398788 cites W2081432561 @default.
• W2967398788 cites W2084853974 @default.
• W2967398788 cites W2085595472 @default.
• W2967398788 cites W2092157292 @default.
• W2967398788 cites W2096747776 @default.
• W2967398788 cites W2107889383 @default.
• W2967398788 cites W2111140026 @default.
• W2967398788 cites W2131350133 @default.
• W2967398788 cites W2131400546 @default.
• W2967398788 cites W2158945597 @default.
• W2967398788 cites W2159458318 @default.
• W2967398788 cites W2160923526 @default.
• W2967398788 cites W2185654598 @default.
• W2967398788 cites W2228286694 @default.
• W2967398788 cites W2230728100 @default.
• W2967398788 cites W2278703703 @default.
• W2967398788 cites W2290495632 @default.
• W2967398788 cites W2313009224 @default.
• W2967398788 cites W2314129795 @default.
• W2967398788 cites W2316125765 @default.
• W2967398788 cites W2320399678 @default.
• W2967398788 cites W2332647335 @default.
• W2967398788 cites W2333656736 @default.
• W2967398788 cites W2395817013 @default.
• W2967398788 cites W2416291895 @default.
• W2967398788 cites W2428223702 @default.
• W2967398788 cites W2505881551 @default.
• W2967398788 cites W2512097316 @default.
• W2967398788 cites W2569742068 @default.
• W2967398788 cites W2575135541 @default.
• W2967398788 cites W2592916788 @default.
• W2967398788 cites W2605476979 @default.
• W2967398788 cites W2624711895 @default.
• W2967398788 cites W2751729666 @default.
• W2967398788 cites W2762424740 @default.
• W2967398788 cites W2793332433 @default.
• W2967398788 cites W2802556414 @default.
• W2967398788 cites W2806626113 @default.
• W2967398788 cites W2885251256 @default.
• W2967398788 cites W2887437777 @default.
• W2967398788 cites W2899600493 @default.
• W2967398788 cites W2907318745 @default.
• W2967398788 doi "https://doi.org/10.1021/acs.organomet.9b00386" @default.
• W2967398788 hasPublicationYear "2019" @default.
• W2967398788 type Work @default.
• W2967398788 sameAs 2967398788 @default.
• W2967398788 citedByCount "8" @default.
• W2967398788 countsByYear W29673987882020 @default.
• W2967398788 countsByYear W29673987882021 @default.
• W2967398788 countsByYear W29673987882022 @default.
• W2967398788 countsByYear W29673987882023 @default.
• W2967398788 crossrefType "journal-article" @default.
• W2967398788 hasAuthorship W2967398788A5013631067 @default.
• W2967398788 hasAuthorship W2967398788A5029673914 @default.
• W2967398788 hasAuthorship W2967398788A5044074956 @default.
• W2967398788 hasAuthorship W2967398788A5053558508 @default.
• W2967398788 hasAuthorship W2967398788A5054638656 @default.
• W2967398788 hasConcept C116569031 @default.
• W2967398788 hasConcept C142724271 @default.
• W2967398788 hasConcept C155647269 @default.

• next