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- W2967400524 endingPage "114110" @default.
- W2967400524 startingPage "114110" @default.
- W2967400524 abstract "Reaction of [{Rh(COD)}2(μ-Cl)2] with 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) has afforded a new organometallic complex [Rh(COD)(dpp-bian)Cl] (1). The crystal structure of 1·0.25H2O was determined by X-ray single crystal analysis. The rhodium(I) ion has a distorted square-pyramidal coordination. The RhCl distance (2.5908 (12) Å) is rather long, indicating weak coordination of the chloride. Dissociation of chloride in solution to produce cationic [Rh(COD)(bian)]+ ([1-Cl]+) was confirmed by ESI-MS, 1H NMR, CV and DFT calculations. Cyclic voltammetry of 1 in acetonitrile (CH3CN) showed two reversible one-electron redox waves at E1/2 = −0.36 V and −1.18 V (versus Ag/AgCl) attributable to successive reduction of the dpp-bian ligand in [1-Cl]+. DFT calculations were performed to explain the anomalously long RhCl distance and interpret the reduction sequence of 1." @default.
- W2967400524 created "2019-08-22" @default.
- W2967400524 creator A5023065023 @default.
- W2967400524 creator A5028321587 @default.
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- W2967400524 creator A5071770414 @default.
- W2967400524 creator A5076287048 @default.
- W2967400524 creator A5076325372 @default.
- W2967400524 date "2019-11-01" @default.
- W2967400524 modified "2023-10-18" @default.
- W2967400524 title "A new organometallic rhodium(I) complex with dpp-bian ligand: Synthesis, structure and redox behaviour" @default.
- W2967400524 cites W1963885927 @default.
- W2967400524 cites W1969360633 @default.
- W2967400524 cites W1972152072 @default.
- W2967400524 cites W1972333269 @default.
- W2967400524 cites W1973423312 @default.
- W2967400524 cites W1974662359 @default.
- W2967400524 cites W1980029154 @default.
- W2967400524 cites W1980743185 @default.
- W2967400524 cites W1985798869 @default.
- W2967400524 cites W1986119632 @default.
- W2967400524 cites W1989270761 @default.
- W2967400524 cites W1995226930 @default.
- W2967400524 cites W1995316733 @default.
- W2967400524 cites W2012319768 @default.
- W2967400524 cites W2022602562 @default.
- W2967400524 cites W2023327948 @default.
- W2967400524 cites W2023525861 @default.
- W2967400524 cites W2025576029 @default.
- W2967400524 cites W2026228805 @default.
- W2967400524 cites W2030327757 @default.
- W2967400524 cites W2033632547 @default.
- W2967400524 cites W2035943899 @default.
- W2967400524 cites W2038994249 @default.
- W2967400524 cites W2041361616 @default.
- W2967400524 cites W2045337789 @default.
- W2967400524 cites W2046702977 @default.
- W2967400524 cites W2048420041 @default.
- W2967400524 cites W2049543666 @default.
- W2967400524 cites W2050442650 @default.
- W2967400524 cites W2050791488 @default.
- W2967400524 cites W2052335941 @default.
- W2967400524 cites W2069839483 @default.
- W2967400524 cites W2073328513 @default.
- W2967400524 cites W2076610279 @default.
- W2967400524 cites W2077453587 @default.
- W2967400524 cites W2078373691 @default.
- W2967400524 cites W2080800869 @default.
- W2967400524 cites W2081329585 @default.
- W2967400524 cites W2090444138 @default.
- W2967400524 cites W2092127932 @default.
- W2967400524 cites W2092157292 @default.
- W2967400524 cites W2096747776 @default.
- W2967400524 cites W2100069387 @default.
- W2967400524 cites W2105072491 @default.
- W2967400524 cites W2108446403 @default.
- W2967400524 cites W2115683954 @default.
- W2967400524 cites W2117397634 @default.
- W2967400524 cites W2117553361 @default.
- W2967400524 cites W2128274661 @default.
- W2967400524 cites W2130254506 @default.
- W2967400524 cites W2133043005 @default.
- W2967400524 cites W2146426024 @default.
- W2967400524 cites W2156676599 @default.
- W2967400524 cites W2160596243 @default.
- W2967400524 cites W2163695728 @default.
- W2967400524 cites W2164982632 @default.
- W2967400524 cites W2165724049 @default.
- W2967400524 cites W2166198169 @default.
- W2967400524 cites W2166291607 @default.
- W2967400524 cites W2170740651 @default.
- W2967400524 cites W2196175606 @default.
- W2967400524 cites W2292328198 @default.
- W2967400524 cites W2292812353 @default.
- W2967400524 cites W2316400394 @default.
- W2967400524 cites W2316431565 @default.
- W2967400524 cites W2318572085 @default.
- W2967400524 cites W2319373097 @default.
- W2967400524 cites W2330047187 @default.
- W2967400524 cites W2521616688 @default.
- W2967400524 cites W2604511868 @default.
- W2967400524 cites W2744331547 @default.
- W2967400524 cites W2746108704 @default.
- W2967400524 cites W2767869999 @default.
- W2967400524 cites W2791916931 @default.
- W2967400524 cites W2793681338 @default.
- W2967400524 cites W2886090699 @default.
- W2967400524 cites W2888839661 @default.
- W2967400524 cites W2949756732 @default.
- W2967400524 cites W4230146992 @default.
- W2967400524 cites W4238969213 @default.
- W2967400524 cites W4255174358 @default.
- W2967400524 cites W4366716132 @default.
- W2967400524 doi "https://doi.org/10.1016/j.poly.2019.114110" @default.
- W2967400524 hasPublicationYear "2019" @default.
- W2967400524 type Work @default.