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- W2967419316 abstract "The level structure of negative-ions near the electron detachment limit dictates the low-energy scattering of an electron with the parent neutral atom. We demonstrate that a single ultracold atom bound inside a Rydberg orbit forming an ultralong-range Rydberg molecule provides an atomic-scale system which is highly sensitive to electron-neutral scattering and thus allows for detailed insights into the underlying near-threshold anion states. Our measurements reveal the so far unobserved fine structure of the $^3P_J$ triplet of Rb$^-$ and allow us to extract parameters of the associated $p$-wave scattering resonances which deviate from previous theoretical estimates. Moreover, we observe a novel alignment mechanism for Rydberg molecules mediated by spin-orbit coupling in the negative ion." @default.
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- W2967419316 date "2019-08-16" @default.
- W2967419316 modified "2023-10-16" @default.
- W2967419316 title "Precision Spectroscopy of Negative-Ion Resonances in Ultralong-Range Rydberg Molecules" @default.
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- W2967419316 doi "https://doi.org/10.1103/physrevlett.123.073003" @default.
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