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- W296750827 abstract "Predicting Efficient Antenna Ligands for Tb(III) Emission Amanda P. S. Samuel, †‡ Jide Xu, † Kenneth N. Raymond †‡ * Contribution from the Department of Chemistry, University of California, Berkeley, CA 94720-1460 raymond@socrates.berkeley.edu RECEIVED DATE (to be automatically inserted after your manuscript is accepted if required according to the journal that you are submitting your paper to) TITLE RUNNING HEAD: Predicting Efficient Antenna Ligands for Tb(III) Emission CORRESPONDING AUTHOR FOOTNOTE: University of California, Berkeley Lawrence Berkeley National Laboratory ABSTRACT: A series of highly luminescent Tb(III) complexes of para-substituted 2- hydroxyisophthalamide ligands (5LI-IAM-X) has been prepared (X = H, CH 3 , (C=O)NHCH 3 , SO 3- , NO 2 , OCH 3 , F, Cl, Br) to probe the effect of substituting the isophthalamide ring on ligand and Tb(III) emission in order to establish a method for predicting the effects of chromophore modification on Tb(III) luminescence. The energies of the ligand singlet and triplet excited states are found to increase linearly with the -withdrawing ability of the substituent. The experimental results are supported by" @default.
- W296750827 created "2016-06-24" @default.
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- W296750827 date "2010-01-14" @default.
- W296750827 modified "2023-09-26" @default.
- W296750827 title "Predicting Efficient Antenna Ligands for Tb(III) Emission" @default.
- W296750827 hasPublicationYear "2010" @default.
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