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- W2967647637 abstract "Abstract The uncatalyzed silylphosphanylation of acetylenic N -trifluoromethylsulfonyl-carboxamides by Ph 2 P–SiMe 3 , formally an insertion of a C,C triple bond into a P–Si bond, is reported. Some characteristic functional group transformations of the resulting 3-PPh 2 -2-SiMe 3 - N -triflyl-acrylamides were briefly explored: transamidation of the N -triflylamide group with allylamine, P oxidation and protodesilylation. A hydrophosphorylation of the acetylenic triple bond with chloro(diphenyl)phosphane is also reported." @default.
- W2967647637 created "2019-08-22" @default.
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- W2967647637 date "2019-08-13" @default.
- W2967647637 modified "2023-10-12" @default.
- W2967647637 title "Phospha-Michael reaction of tertiary phosphanes Ph2P–X (X=SiMe3, Cl) and N-triflyl-propiolamides" @default.
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- W2967647637 doi "https://doi.org/10.1515/znb-2019-0100" @default.
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