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- W2967808220 endingPage "13336" @default.
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- W2967808220 abstract "A tridentate benzoxazole-containing aminophenol ligand NNOH2 was coordinated to Co and V metal centers and the electronic structure of the resultant complexes characterized by both experimental and theoretical methods. The solid state structure of the Co complex exhibits a distorted octahedral geometry with two tridentate ligands bound in meridional fashion, and coordination-sphere bond lengths consistent with a Co(iii) oxidation state. EPR and magnetic data support a S = 1/2 ground state, and a formal electronic description of Co(iii)(NNOAP)(NNOISQ) where NNOAP corresponds to an amidophenoxide and NNOISQ to the iminosemiquinone redox level. However, the metrical parameters are similar for both ligands in the solid state, and DFT calculations support delocalization of the ligand radical over both ligands, affording an intermediate ligand redox level Co(iii)(NNO1.5-)(NNO1.5-). The vanadyl complex exhibits a distorted octahedral geometry in the solid state consistent with a V(v) metal center and amidophenoxide (NNOAP), acetylacetonate and oxo ligands. The ligand metrical parameters are consistent with significant amidophenoxide to V(v) π donation. Overall, our results highlight the roles of electron transfer, delocalization, and π bonding in the metal complexes under study, and thus the complexity in assignment of the electronic structure in these systems." @default.
- W2967808220 created "2019-08-22" @default.
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- W2967808220 creator A5083010457 @default.
- W2967808220 date "2019-01-01" @default.
- W2967808220 modified "2023-09-26" @default.
- W2967808220 title "Stabilization of different redox levels of a tridentate benzoxazole amidophenoxide ligand when bound to Co(<scp>iii</scp>) or V(<scp>v</scp>)" @default.
- W2967808220 cites W1965126823 @default.
- W2967808220 cites W1965476996 @default.
- W2967808220 cites W1966174040 @default.
- W2967808220 cites W1968400590 @default.
- W2967808220 cites W1970225878 @default.
- W2967808220 cites W1979931992 @default.
- W2967808220 cites W1981712030 @default.
- W2967808220 cites W1987658587 @default.
- W2967808220 cites W1987702006 @default.
- W2967808220 cites W1990435926 @default.
- W2967808220 cites W1994691835 @default.
- W2967808220 cites W1997154912 @default.
- W2967808220 cites W1997295141 @default.
- W2967808220 cites W1997530181 @default.
- W2967808220 cites W1998481284 @default.
- W2967808220 cites W1998521994 @default.
- W2967808220 cites W1998594758 @default.
- W2967808220 cites W2002407275 @default.
- W2967808220 cites W2004626073 @default.
- W2967808220 cites W2006653538 @default.
- W2967808220 cites W2010166323 @default.
- W2967808220 cites W2011252023 @default.
- W2967808220 cites W2014338134 @default.
- W2967808220 cites W2015697377 @default.
- W2967808220 cites W2017077641 @default.
- W2967808220 cites W2019354728 @default.
- W2967808220 cites W2019398921 @default.
- W2967808220 cites W2021502908 @default.
- W2967808220 cites W2022547257 @default.
- W2967808220 cites W2023427840 @default.
- W2967808220 cites W2023983447 @default.
- W2967808220 cites W2025624195 @default.
- W2967808220 cites W2027063055 @default.
- W2967808220 cites W2027557262 @default.
- W2967808220 cites W2028832730 @default.
- W2967808220 cites W2030054392 @default.
- W2967808220 cites W2032302694 @default.
- W2967808220 cites W2040367489 @default.
- W2967808220 cites W2041678746 @default.
- W2967808220 cites W2041987581 @default.
- W2967808220 cites W2047853910 @default.
- W2967808220 cites W2048972542 @default.
- W2967808220 cites W2049147267 @default.
- W2967808220 cites W2058210956 @default.
- W2967808220 cites W2058680766 @default.
- W2967808220 cites W2058964453 @default.
- W2967808220 cites W2059020082 @default.
- W2967808220 cites W2063663126 @default.
- W2967808220 cites W2064343845 @default.
- W2967808220 cites W2065205106 @default.
- W2967808220 cites W2066426638 @default.
- W2967808220 cites W2067120101 @default.
- W2967808220 cites W2070290220 @default.
- W2967808220 cites W2070365441 @default.
- W2967808220 cites W2071665522 @default.
- W2967808220 cites W2071916546 @default.
- W2967808220 cites W2073793481 @default.
- W2967808220 cites W2074102409 @default.
- W2967808220 cites W2075043120 @default.
- W2967808220 cites W2075784213 @default.
- W2967808220 cites W2077059894 @default.
- W2967808220 cites W2078146328 @default.
- W2967808220 cites W2080182825 @default.
- W2967808220 cites W2080307773 @default.
- W2967808220 cites W2084600364 @default.
- W2967808220 cites W2088505060 @default.
- W2967808220 cites W2088866503 @default.
- W2967808220 cites W2090309515 @default.
- W2967808220 cites W2091829211 @default.
- W2967808220 cites W2092531318 @default.
- W2967808220 cites W2093866819 @default.
- W2967808220 cites W2095474273 @default.
- W2967808220 cites W2098972007 @default.
- W2967808220 cites W2103029770 @default.
- W2967808220 cites W2111918052 @default.
- W2967808220 cites W2114953205 @default.
- W2967808220 cites W2118837742 @default.
- W2967808220 cites W2121241715 @default.
- W2967808220 cites W2122078186 @default.
- W2967808220 cites W2122135897 @default.
- W2967808220 cites W2135517062 @default.
- W2967808220 cites W2140485401 @default.
- W2967808220 cites W2141000662 @default.