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• W2967862364 endingPage "15371" @default.
• W2967862364 startingPage "15367" @default.
• W2967862364 abstract "Abstract An NHC‐coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon‐soluble monomeric Au I hydride, which readily adds CO 2 at room temperature yielding the corresponding Au I formate. The reversible reaction can be expedited by the addition of NHC, which induces β‐hydride shift and the removal of CO 2 from equilibrium through the formation of an NHC‐CO 2 adduct. The Au I formate is alternatively formed by dehydrogenative coupling of the Au I hydride with formic acid (HCO 2 H), thus in total establishing a reaction sequence for the Au I hydride mediated dehydrogenation of HCO 2 H as chemical hydrogen storage material." @default.
• W2967862364 created "2019-08-22" @default.
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• W2967862364 date "2019-09-12" @default.
• W2967862364 modified "2023-10-01" @default.
• W2967862364 title "NHC‐Coordinated Diphosphene‐Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO₂" @default.
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• W2967862364 doi "https://doi.org/10.1002/anie.201909798" @default.
• W2967862364 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6916326" @default.
• W2967862364 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31414524" @default.
• W2967862364 hasPublicationYear "2019" @default.
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