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- W2967869912 abstract "Abstract The synthesis of TBA‐DASA‐POM‐DASA , the first photoactive covalent hybrid polyoxometalate (POM) incorporating a donor–acceptor Stenhouse adduct (DASA) reverse photochrome, is presented. It has been evidenced that in solution the equilibrium between the colorless cyclopentenone and the highly colored triene conformers is strongly dependent not only on the nature of the solvent but also the countercations, allowing to tune its optical properties. This complex has been further associated to photochromic spironaphtoxazine cations, resulting in a material which can be activated by two distinct optical stimuli. Moreover, when combined with N ‐methyldiethanolamine, TBA‐DASA‐POM‐DASA constitutes a performing photoinitiating system for polyethylene glycol diacrylate polymerization and under visible light irradiation, a promising result in a domain scarcely developed in POM chemistry." @default.
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- W2967869912 date "2019-10-09" @default.
- W2967869912 modified "2023-10-18" @default.
- W2967869912 title "Photoactive Polyoxometalate/DASA Covalent Hybrids for Photopolymerization in the Visible Range" @default.
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- W2967869912 doi "https://doi.org/10.1002/chem.201902573" @default.
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