Matches in SemOpenAlex for { <https://semopenalex.org/work/W2968213989> ?p ?o ?g. }
- W2968213989 endingPage "3319" @default.
- W2968213989 startingPage "3313" @default.
- W2968213989 abstract "Abstract Unusual 1,2‐migration reactions of N‐heterocyclic carbene (NHC) on transition metals were investigated using density functional theory calculations. Our results reveal that the electronic properties, ring strain of the four‐membered ring, and aromaticity of NHC play crucial roles in the thermodynamics of such a 1,2‐migration. Further studies show that changing the methylene on the metal center in the reactant with a more electronegative group (NH or O) will lead to the formation of products with nitrogen coordinating to the metal center, whereas other groups (BH, CF 2 , and SiH 2 ) will make such a 1,2‐migration reverse. In addition, the reversed rearrangement of 1,2‐boron, silyl migration could be thermodynamically and kinetically favorable." @default.
- W2968213989 created "2019-08-22" @default.
- W2968213989 creator A5012980782 @default.
- W2968213989 creator A5045317640 @default.
- W2968213989 creator A5070730575 @default.
- W2968213989 creator A5075578352 @default.
- W2968213989 date "2019-08-29" @default.
- W2968213989 modified "2023-10-08" @default.
- W2968213989 title "Reaction Mechanisms on Unusual 1,2‐Migrations of N‐Heterocyclic Carbene‐Ligated Transition Metal Complexes" @default.
- W2968213989 cites W1549013657 @default.
- W2968213989 cites W1966182479 @default.
- W2968213989 cites W1966444728 @default.
- W2968213989 cites W1966983316 @default.
- W2968213989 cites W1967253297 @default.
- W2968213989 cites W1970979049 @default.
- W2968213989 cites W1981745234 @default.
- W2968213989 cites W1991312972 @default.
- W2968213989 cites W1992173555 @default.
- W2968213989 cites W1992996188 @default.
- W2968213989 cites W1993383767 @default.
- W2968213989 cites W1996618874 @default.
- W2968213989 cites W1997151511 @default.
- W2968213989 cites W2003555872 @default.
- W2968213989 cites W2005227604 @default.
- W2968213989 cites W2008423326 @default.
- W2968213989 cites W2014312532 @default.
- W2968213989 cites W2018609658 @default.
- W2968213989 cites W2027066802 @default.
- W2968213989 cites W2038092103 @default.
- W2968213989 cites W2042481895 @default.
- W2968213989 cites W2042558692 @default.
- W2968213989 cites W2042944554 @default.
- W2968213989 cites W2043681561 @default.
- W2968213989 cites W2043935388 @default.
- W2968213989 cites W2049996223 @default.
- W2968213989 cites W2056169295 @default.
- W2968213989 cites W2057370118 @default.
- W2968213989 cites W2061565329 @default.
- W2968213989 cites W2067728662 @default.
- W2968213989 cites W2070005238 @default.
- W2968213989 cites W2074035162 @default.
- W2968213989 cites W2081540873 @default.
- W2968213989 cites W2089759714 @default.
- W2968213989 cites W2102262124 @default.
- W2968213989 cites W2112625081 @default.
- W2968213989 cites W2113057417 @default.
- W2968213989 cites W2131937366 @default.
- W2968213989 cites W2132525235 @default.
- W2968213989 cites W2135663026 @default.
- W2968213989 cites W2135893605 @default.
- W2968213989 cites W2149783350 @default.
- W2968213989 cites W2156475195 @default.
- W2968213989 cites W2162677265 @default.
- W2968213989 cites W2164318957 @default.
- W2968213989 cites W2299637886 @default.
- W2968213989 cites W2312791962 @default.
- W2968213989 cites W2319383662 @default.
- W2968213989 cites W2461223532 @default.
- W2968213989 cites W2492185691 @default.
- W2968213989 cites W2783530098 @default.
- W2968213989 cites W2796490411 @default.
- W2968213989 cites W2917008697 @default.
- W2968213989 cites W2923715876 @default.
- W2968213989 cites W2932006940 @default.
- W2968213989 cites W2944267677 @default.
- W2968213989 cites W2946012279 @default.
- W2968213989 cites W2952502872 @default.
- W2968213989 cites W4211172071 @default.
- W2968213989 cites W4252752564 @default.
- W2968213989 cites W628009773 @default.
- W2968213989 doi "https://doi.org/10.1002/asia.201900895" @default.
- W2968213989 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31414563" @default.
- W2968213989 hasPublicationYear "2019" @default.
- W2968213989 type Work @default.
- W2968213989 sameAs 2968213989 @default.
- W2968213989 citedByCount "7" @default.
- W2968213989 countsByYear W29682139892019 @default.
- W2968213989 countsByYear W29682139892021 @default.
- W2968213989 countsByYear W29682139892022 @default.
- W2968213989 countsByYear W29682139892023 @default.
- W2968213989 crossrefType "journal-article" @default.
- W2968213989 hasAuthorship W2968213989A5012980782 @default.
- W2968213989 hasAuthorship W2968213989A5045317640 @default.
- W2968213989 hasAuthorship W2968213989A5070730575 @default.
- W2968213989 hasAuthorship W2968213989A5075578352 @default.
- W2968213989 hasConcept C106773901 @default.
- W2968213989 hasConcept C107111320 @default.
- W2968213989 hasConcept C147597530 @default.
- W2968213989 hasConcept C152365726 @default.
- W2968213989 hasConcept C155647269 @default.
- W2968213989 hasConcept C161790260 @default.
- W2968213989 hasConcept C178790620 @default.
- W2968213989 hasConcept C185592680 @default.
- W2968213989 hasConcept C192386470 @default.
- W2968213989 hasConcept C2777164566 @default.
- W2968213989 hasConcept C2777454769 @default.
- W2968213989 hasConcept C2779463800 @default.
- W2968213989 hasConcept C2780378348 @default.