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- W2968275839 endingPage "126932" @default.
- W2968275839 startingPage "126932" @default.
- W2968275839 abstract "Herein, we have synthesized a new dimeric rhodium(III) triphenylphospine complex, [Rh2(PPh3)2(L)2Cl2] (1) via sp3(C)–S bond cleavage of a thioether containing ligand, 1-(((2-(ethylthio)phenyl)diazenyl)methyl)naphthalen-2-ol (L-CH2CH3). The complex was thoroughly characterized by using various spectroscopic techniques. Dimeric structure with distorted octahedral geometry of each of the rhodium center is confirmed by single crystal X-ray diffraction method. Catalytic efficiency of the complex towards transfer hydrogenation of ketones is studied in i-PrOH. Electronic structure and UV–vis spectrum of the complex are interpreted by DFT and TDDFT computations." @default.
- W2968275839 created "2019-08-22" @default.
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- W2968275839 date "2019-12-01" @default.
- W2968275839 modified "2023-09-27" @default.
- W2968275839 title "Synthesis of thiolato bridged dimeric rhodium(III) triphenylphosphine complex via C–S bond cleavage: X-ray structure, DFT computation and catalytic evaluation towards transfer hydrogenation of ketones" @default.
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- W2968275839 doi "https://doi.org/10.1016/j.molstruc.2019.126932" @default.
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