FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2968312610> ?p ?o ?g. }

• W2968312610 endingPage "109348" @default.
• W2968312610 startingPage "109348" @default.
• W2968312610 abstract "This work evaluates the feasibility of a solar-enhanced Fenton-like process using S2O82- (PS) and Fe2+ for the elimination of BPA, a model endocrine-disruption compound. This comparative study of BPA removal showed that among the approaches employed, the effectiveness of BPA degradation (10 mg/L) decreased in the order: Solar/PS/Fe2+> Solar/PS > PS/Fe2+> Solar/Fe2+> Solar. The complete degradation of BPA was achieved by Solar/PS/Fe2+ treatment at a [PS]:[BPA] ratio of 20 in less than t30W 5 in deionised water. The high efficiency of the Solar/PS/Fe2+ process revealed a synergistic effect (ϕ = 2.38) between the applied activation agents on the formation of reactive oxygen species (ROS) and subsequent decomposition of BPA. The treatment was accompanied by total organic carbon (TOC) removal (44%) in 45 min. Sequential generation of reactive oxygen species has made Solar/PS/Fe2+ a kinetically effective process for removing BPA without accumulation of toxic intermediates. The reaction rate followed pseudo-first-order kinetics that increased with increasing PS and Fe2+ concentrations. Experimental evidence suggests that exposure to solar irradiation maintains suitable quantities of free Fe2+ in the reaction mixture, even at low catalyst concentrations (the molar ratio of [PS]:[Fe2+] varied from 1:0.01 to 1:0.08). The effects of HCO3-, SO42-, and Cl- were also examined. As expected, HCO3- and SO42- inhibited BPA oxidation. The effect of Cl- on the oxidation efficiency of BPA in Fenton-like systems depends not only on actual Cl- concentrations but it is also highly influenced by molar ratios of Cl- to oxidant and catalyst. Inhibition, which was caused by Cl- in the mM range can be overcome by prolonging the reaction time or increasing the initial Fe2+concentration. Finally, the efficiency of Solar/PS/Fe2+ process was examined in diluted natural surface water and wastewater effluent. On eliminating the buffering action of HCO3-/CO32- ions by lowering the pH value to 4.5, complete BPA degradation was achieved in all real water matrices." @default.
• W2968312610 created "2019-08-22" @default.
• W2968312610 creator A5001708919 @default.
• W2968312610 creator A5003292455 @default.
• W2968312610 creator A5061644200 @default.
• W2968312610 creator A5083721870 @default.
• W2968312610 creator A5086851272 @default.
• W2968312610 date "2019-11-01" @default.
• W2968312610 modified "2023-10-12" @default.
• W2968312610 title "Photo-Fenton-like degradation of bisphenol A by persulfate and solar irradiation" @default.
• W2968312610 cites W1964489774 @default.
• W2968312610 cites W1964631634 @default.
• W2968312610 cites W1964675752 @default.
• W2968312610 cites W1966973107 @default.
• W2968312610 cites W1967091842 @default.
• W2968312610 cites W1969565930 @default.
• W2968312610 cites W1969922892 @default.
• W2968312610 cites W1980435932 @default.
• W2968312610 cites W1981163594 @default.
• W2968312610 cites W1983228601 @default.
• W2968312610 cites W1985146037 @default.
• W2968312610 cites W1985161820 @default.
• W2968312610 cites W2009571045 @default.
• W2968312610 cites W2014279738 @default.
• W2968312610 cites W2022176716 @default.
• W2968312610 cites W2023441217 @default.
• W2968312610 cites W2029216814 @default.
• W2968312610 cites W2030683065 @default.
• W2968312610 cites W2030946379 @default.
• W2968312610 cites W2032652071 @default.
• W2968312610 cites W2033413314 @default.
• W2968312610 cites W2034079702 @default.
• W2968312610 cites W2038617130 @default.
• W2968312610 cites W2040167924 @default.
• W2968312610 cites W2040601409 @default.
• W2968312610 cites W2047836668 @default.
• W2968312610 cites W2048888892 @default.
• W2968312610 cites W2049135609 @default.
• W2968312610 cites W2054642659 @default.
• W2968312610 cites W2062286136 @default.
• W2968312610 cites W2062288824 @default.
• W2968312610 cites W2063690478 @default.
• W2968312610 cites W2063852494 @default.
• W2968312610 cites W2067692229 @default.
• W2968312610 cites W2069697796 @default.
• W2968312610 cites W2069932480 @default.
• W2968312610 cites W2070270288 @default.
• W2968312610 cites W2071564182 @default.
• W2968312610 cites W2073444037 @default.
• W2968312610 cites W2081114557 @default.
• W2968312610 cites W2081709688 @default.
• W2968312610 cites W2082877207 @default.
• W2968312610 cites W2088635029 @default.
• W2968312610 cites W2090754139 @default.
• W2968312610 cites W2110456741 @default.
• W2968312610 cites W2112334680 @default.
• W2968312610 cites W2118028477 @default.
• W2968312610 cites W2145415601 @default.
• W2968312610 cites W2157189768 @default.
• W2968312610 cites W2168099462 @default.
• W2968312610 cites W2289959226 @default.
• W2968312610 cites W2298431938 @default.
• W2968312610 cites W2300593429 @default.
• W2968312610 cites W2319229163 @default.
• W2968312610 cites W2335018440 @default.
• W2968312610 cites W2396459835 @default.
• W2968312610 cites W2411369509 @default.
• W2968312610 cites W2508930034 @default.
• W2968312610 cites W2537470019 @default.
• W2968312610 cites W2548533667 @default.
• W2968312610 cites W2556065164 @default.
• W2968312610 cites W2565908047 @default.
• W2968312610 cites W2606654680 @default.
• W2968312610 cites W2609145994 @default.
• W2968312610 cites W2736371272 @default.
• W2968312610 cites W2738104932 @default.
• W2968312610 cites W2739606443 @default.
• W2968312610 cites W2752835429 @default.
• W2968312610 cites W2756453752 @default.
• W2968312610 cites W2757759314 @default.
• W2968312610 cites W2758000294 @default.
• W2968312610 cites W2768080672 @default.
• W2968312610 cites W2772269479 @default.
• W2968312610 cites W2782270482 @default.
• W2968312610 cites W2782479753 @default.
• W2968312610 cites W2791309021 @default.
• W2968312610 cites W2793647974 @default.
• W2968312610 cites W2810999214 @default.
• W2968312610 cites W2886210266 @default.
• W2968312610 cites W2895079246 @default.
• W2968312610 cites W2933444205 @default.
• W2968312610 cites W2949011086 @default.
• W2968312610 cites W2951786232 @default.
• W2968312610 cites W2997563712 @default.
• W2968312610 cites W2096857421 @default.
• W2968312610 cites W2531473195 @default.
• W2968312610 doi "https://doi.org/10.1016/j.jenvman.2019.109348" @default.
• W2968312610 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31430624" @default.

• next