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- W2968354826 abstract "We describe the catalytic amination of β-(hetero)arylethyl ethers with amines using the organic superbase t-Bu-P4 to obtain β-(hetero)arylethylamines. The reaction has a broad substrate scope and allows the transformations of electron-deficient and electron-neutral β-(hetero)arylethyl ethers with various amines including pyrrole, N-alkylaniline, diphenylamine, aniline, indole, and indoline derivatives. Mechanistic studies indicate a two-reaction pathway of MeOH elimination from the substrate to form a (hetero)arylalkene followed by the hydroamination of the alkene." @default.
- W2968354826 created "2019-08-22" @default.
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- W2968354826 date "2019-08-12" @default.
- W2968354826 modified "2023-10-16" @default.
- W2968354826 title "Catalytic Amination of β-(Hetero)arylethyl Ethers by Phosphazene Base <i>t</i>-Bu-P4" @default.
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- W2968354826 doi "https://doi.org/10.1021/acs.orglett.9b02309" @default.
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