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• W2968481104 endingPage "178354" @default.
• W2968481104 startingPage "178354" @default.
• W2968481104 abstract "The thermal behaviors of benzoyl peroxide (BPO) under contamination have been a topic received extensive attention. This paper attempted to examine the effect of phenol on the decomposition reaction of BPO by applying dynamic, isothermal DSC experiments and slow cook-off test. A kinetic model was further established by the Thermal Safety Software through fitting DSC curves and verified by the slow cook-off test. Moreover, the runaway reactions under different storage conditions were predicted. The results indicate that the phenol significantly reduces the thermal stability of BPO and the Benito-Perez model is credible to evaluate the decomposition process. During simulating the reaction process, it is predicted that the explosion could take place even at the 40 °C for 50 kg packaging sample. For 10% limit value, the time to conversion limit of sample is 7.49 h at 40 °C, while it just only 2.37 h at 110 °C." @default.
• W2968481104 created "2019-08-22" @default.
• W2968481104 creator A5007213303 @default.
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• W2968481104 date "2019-11-01" @default.
• W2968481104 modified "2023-10-06" @default.
• W2968481104 title "Thermal risk analysis of benzoyl peroxide in the presence of phenol: Based on the experimental and simulation approach" @default.
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• W2968481104 doi "https://doi.org/10.1016/j.tca.2019.178354" @default.
• W2968481104 hasPublicationYear "2019" @default.
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