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• W2968499548 abstract "A soluble well-defined 9,10-diphenylanthryl-bridged ladder polysiloxane (DPAnLP) was prepared via supramolecular assembly-directed condensation polymerization of silanols. The ladder superstructure (LS) was obtained via a synergistic interaction of H-bonding and π-π stacking between polymerizable precursor 2-tert-butyl-9,10-bis(methyldihydroxylsilyl)anthracene in organic solvent. The resultant LS was then used as template to direct the condensation of silanol groups to obtain DPAnLP with high regularity. It was found that DPAnLP can emit blue light (430 nm) with great stability and high efficiency in both solution and solid film, which indicated a well organizing of fluorophore within confined environment (ladder structure). TGA and DSC measurements showed that DPAnLP had good thermal stability, and cyclic voltammetry detection gave a low-lying highest occupied molecular orbital level." @default.
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• W2968499548 date "2010-01-01" @default.
• W2968499548 modified "2023-09-23" @default.
• W2968499548 title "Supramolecular template-directed synthesis of stable and high-efficiency photoluminescence 9,10-diphenylanthryl-bridged ladder polysiloxane Part A Polymer chemistry" @default.
• W2968499548 hasPublicationYear "2010" @default.
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