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- W2968647488 abstract "Abstract The twofold hydroboration products of (Fmes)BH 2 ⋅SMe 2 with a series of alkynes (2‐butyne, arylethynes) react with two molar equiv of 2,6‐dimethylphenyl isocyanide (CN‐Xyl) at 80 °C to give rare examples of 1,3‐azaborinine derivatives. A mechanistic study revealed a reaction course involving insertion of one isonitrile followed by a bora‐Nazarov type ring‐closure reaction and subsequent isonitrile insertion to give the respective 1,3‐dihydro‐1,3‐azaborinines 5 ." @default.
- W2968647488 created "2019-08-22" @default.
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- W2968647488 date "2019-09-12" @default.
- W2968647488 modified "2023-10-12" @default.
- W2968647488 title "Multi‐Component Synthesis of Rare 1,3‐Dihydro‐1,3‐azaborinine Derivatives: Application of a Bora‐Nazarov Type Reaction" @default.
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- W2968647488 doi "https://doi.org/10.1002/anie.201909530" @default.
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