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• W2968704986 abstract "Abstract In this paper, Ti-V-Co and Ti-V-Ni-Co alloys are considered as the hydrogen storage systems and the negative electrodes in Ni-MH x secondary batteries. This work shows results of studies that have been made on Ti 0.5 V 1.5− x Co x and Ti 0.5 V 1.4− x Ni 0.1 Co x nanocrystalline alloys ( x = 0, 0.1 0.2, 0.3) synthesized by the mechanical alloying technique. The goal of this study is to determine an effect of partial replacement of V by Co atoms on hydrogen storage and electrochemical properties of Ti-V and Ti-V-Ni alloys. X-ray diffraction studies have proven that 14 h of the ball milling has resulted in crystallization of body-centered-cubic solid solution. Studies performed on high-resolution transmission electron microscope confirm creation of nanocrystalline materials. Hydrogen sorption/desorption measurements that have been performed at 303 K show that Co accelerates the hydrogen sorption process, diminishes hysteresis and ameliorates the hydrogen storage reversibility. Properties of Ti-V-Co alloys, described in this work, originate mainly from structure of these materials. Electrochemical measurements of Ti-V-Co alloys have shown these materials poorly absorb hydrogen in 6 M KOH solution. Ti 0.5 V 1.4− x Ni 0.1 Co x alloys are characterized by better activation properties and improved cyclability in comparison to Co-free Ti 0.5 V 1.4 Ni 0.1 alloy." @default.
• W2968704986 created "2019-08-22" @default.
• W2968704986 creator A5052752656 @default.
• W2968704986 date "2019-08-12" @default.
• W2968704986 modified "2023-09-27" @default.
• W2968704986 title "Structural, Electrochemical and Hydrogen Sorption Studies of Nanocrystalline Ti-V-Co and Ti-V-Ni-Co Alloys Synthesized by Mechanical Alloying Method" @default.
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• W2968704986 doi "https://doi.org/10.1007/s11665-019-04266-x" @default.
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