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- W2968716071 abstract "Abstract An arrestive 2-picolinic acid functionalized 3d–4f heterometallic germanotungstate based on plenary α-Keggin [GeW12O40]4− polyanion [Cu2(PA)3(H2O)3][Gd(H2O)8]0.5[Cu2(PA)3(H2O)4]H0.5[α-GeW12O40]·5H2O (1) was synthesized by reaction of Na2WO4·2H2O, GeO2, Gd(NO3)3·6H2O, CuCl2·2H2O and 2-picolinic acid (HPA) in aqueous solution. The polyoxoanion unit of 1 consists of a plenary Keggin [α-GeW12O40]4− anion with a decorated [Cu2(PA)3(H2O)3]+ cation and a decorated 3d–4f heterometallic {[Gd(H2O)8]0.5[Cu2(PA)3(H2O)4]}2.5+ segment and neighboring polyoxoanion units are further expanded into a 1-D chain alignment through unique bridging di‑copper [Cu2(PA)3(H2O)3]+ linkers. Furthermore, the electrochemical properties of the 1@CMWCNTs–Nafion/GCE electrochemical sensor was investigated, which shows a good stability and a good sensing performance toward the dopamine detection. This research offers the possibility of organic–inorganic hybrid heterometallic germanotungstates for serving as electrode response materials." @default.
- W2968716071 created "2019-08-22" @default.
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- W2968716071 date "2019-10-01" @default.
- W2968716071 modified "2023-10-16" @default.
- W2968716071 title "A novel inorganic–organic hybrid 3d–4f heterometallic germanotungstate based on saturated Keggin-type [α-GeW12O40]4− polyanion" @default.
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- W2968716071 doi "https://doi.org/10.1016/j.inoche.2019.107542" @default.
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