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- W2968734129 abstract "Abstract Four mono- and bi-nuclear lanthanide complexes [LnL1(NO3) (H2O)DMF] (Ln = Nd (1) and Yb (2)) and [Ln2 (L2)2(OAc)2] (Ln = Nd (3) and Yb (4)) were synthesized by using two new Schiff base ligands with long (CH2)2NH(CH2)2 backbone. The lengths of the Schiff base ligands are about 1.8 nm. The bi-nuclear lanthanide complexes 3 and 4 have nanoscale structures with sizes of approximately 0.7 nm × 1.1 nm × 1.6 nm. For 3, the molar ratio of Nd:Br:O obtained by the energy dispersive X-ray spectroscopy analysis is in agreement with the crystal structure. The chromogenic Schiff base ligands in 1–4 can efficiently transfer energy to lanthanide ions, thus, these complexes exhibit the typical NIR luminescence of lanthanide ions. Interestingly, 3 and 4 have higher NIR emission quantum yields (Φem) than 1 and 2, respectively." @default.
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- W2968734129 date "2020-02-01" @default.
- W2968734129 modified "2023-10-17" @default.
- W2968734129 title "Construction of NIR luminescent nanoscale lanthanide complexes with new flexible Schiff base ligands" @default.
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- W2968734129 doi "https://doi.org/10.1016/j.jre.2019.02.014" @default.
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