Matches in SemOpenAlex for { <https://semopenalex.org/work/W2968955306> ?p ?o ?g. }
- W2968955306 abstract "Reactions of 2‐[1‐(3,5‐dimethylpyrazol‐1‐yl)ethyl]pyridine (L1) and 2‐[1‐(3,5‐diphenylpyrazol‐1‐yl)ethyl]pyridine (L2) with the [Pd (COD)Cl 2 ] or [Pd (COD)MeCl] produced palladium (II) complexes [Pd( L1 )ClMe] ( 1 ), [Pd( L1 )Cl 2 ] ( C2 ), [Pd( L2 )ClMe] ( 3 ), and [Pd( L2 )Cl 2 ] ( 4 ) in quantitative yields. Solid state structures of complexes 1 , 3 and 4 established the formation of mononuclear compounds, containing one bidentate ligand unit per metal atom, to give square planar complexes. All the other spectroscopic characterization data and elemental analyses were consistent with the observed structures. All the palladium (II) complexes 1–4 gave active catalysts in the methoxycarbonylation of 1‐octenes. The catalysts demonstrated 100% chemoselectivities towards esters and favored the formation of linear isomers. Reaction conditions such as the type of phosphine derivative, acid promoter, solvent system, time, pressure and temperature have been investigated and shown to affect both the catalytic activity and regio‐selectivity of the catalysts. Solid‐angle modelling established the comparable steric contributions from the ligands, consistent with the similar regioselectivities of the resultant catalysts." @default.
- W2968955306 created "2019-08-22" @default.
- W2968955306 creator A5004988621 @default.
- W2968955306 creator A5016344821 @default.
- W2968955306 creator A5045488730 @default.
- W2968955306 creator A5059636986 @default.
- W2968955306 date "2019-08-16" @default.
- W2968955306 modified "2023-09-26" @default.
- W2968955306 title "Structural and theoretical studies of the methoxycarbonylation of higher olefins catalysed by (Pyrazolyl‐ethyl)pyridine palladium (II) complexes" @default.
- W2968955306 cites W1954792166 @default.
- W2968955306 cites W1964610021 @default.
- W2968955306 cites W1966182479 @default.
- W2968955306 cites W1966363887 @default.
- W2968955306 cites W1971275758 @default.
- W2968955306 cites W1975708211 @default.
- W2968955306 cites W1978890358 @default.
- W2968955306 cites W1979368277 @default.
- W2968955306 cites W1981368803 @default.
- W2968955306 cites W1986119632 @default.
- W2968955306 cites W1990170643 @default.
- W2968955306 cites W1996843768 @default.
- W2968955306 cites W2001449419 @default.
- W2968955306 cites W2013464543 @default.
- W2968955306 cites W2016978656 @default.
- W2968955306 cites W2027574036 @default.
- W2968955306 cites W2036637995 @default.
- W2968955306 cites W2038019944 @default.
- W2968955306 cites W2042128643 @default.
- W2968955306 cites W2044490585 @default.
- W2968955306 cites W2046528962 @default.
- W2968955306 cites W2054704030 @default.
- W2968955306 cites W2058147103 @default.
- W2968955306 cites W2068617439 @default.
- W2968955306 cites W2073967359 @default.
- W2968955306 cites W2075899003 @default.
- W2968955306 cites W2079306804 @default.
- W2968955306 cites W2086200756 @default.
- W2968955306 cites W2103709892 @default.
- W2968955306 cites W2114436359 @default.
- W2968955306 cites W2126483141 @default.
- W2968955306 cites W2129706224 @default.
- W2968955306 cites W2136251418 @default.
- W2968955306 cites W2144442846 @default.
- W2968955306 cites W2145538332 @default.
- W2968955306 cites W2148550585 @default.
- W2968955306 cites W2162168558 @default.
- W2968955306 cites W2217131756 @default.
- W2968955306 cites W2280367163 @default.
- W2968955306 cites W2286963838 @default.
- W2968955306 cites W2302054269 @default.
- W2968955306 cites W2405666681 @default.
- W2968955306 cites W2517470579 @default.
- W2968955306 cites W2522852670 @default.
- W2968955306 cites W2524131785 @default.
- W2968955306 cites W2582411146 @default.
- W2968955306 cites W2584613314 @default.
- W2968955306 cites W2737953737 @default.
- W2968955306 cites W2738089293 @default.
- W2968955306 cites W2790004787 @default.
- W2968955306 cites W584342613 @default.
- W2968955306 doi "https://doi.org/10.1002/aoc.5175" @default.
- W2968955306 hasPublicationYear "2019" @default.
- W2968955306 type Work @default.
- W2968955306 sameAs 2968955306 @default.
- W2968955306 citedByCount "7" @default.
- W2968955306 countsByYear W29689553062020 @default.
- W2968955306 countsByYear W29689553062021 @default.
- W2968955306 countsByYear W29689553062022 @default.
- W2968955306 countsByYear W29689553062023 @default.
- W2968955306 crossrefType "journal-article" @default.
- W2968955306 hasAuthorship W2968955306A5004988621 @default.
- W2968955306 hasAuthorship W2968955306A5016344821 @default.
- W2968955306 hasAuthorship W2968955306A5045488730 @default.
- W2968955306 hasAuthorship W2968955306A5059636986 @default.
- W2968955306 hasConcept C116569031 @default.
- W2968955306 hasConcept C118792377 @default.
- W2968955306 hasConcept C155647269 @default.
- W2968955306 hasConcept C161790260 @default.
- W2968955306 hasConcept C168382676 @default.
- W2968955306 hasConcept C170493617 @default.
- W2968955306 hasConcept C178516000 @default.
- W2968955306 hasConcept C178790620 @default.
- W2968955306 hasConcept C185592680 @default.
- W2968955306 hasConcept C201194858 @default.
- W2968955306 hasConcept C2777716191 @default.
- W2968955306 hasConcept C2779485729 @default.
- W2968955306 hasConcept C2780471494 @default.
- W2968955306 hasConcept C502130503 @default.
- W2968955306 hasConcept C512735826 @default.
- W2968955306 hasConcept C544153396 @default.
- W2968955306 hasConcept C55493867 @default.
- W2968955306 hasConcept C71240020 @default.
- W2968955306 hasConceptScore W2968955306C116569031 @default.
- W2968955306 hasConceptScore W2968955306C118792377 @default.
- W2968955306 hasConceptScore W2968955306C155647269 @default.
- W2968955306 hasConceptScore W2968955306C161790260 @default.
- W2968955306 hasConceptScore W2968955306C168382676 @default.
- W2968955306 hasConceptScore W2968955306C170493617 @default.
- W2968955306 hasConceptScore W2968955306C178516000 @default.
- W2968955306 hasConceptScore W2968955306C178790620 @default.