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• W2969014695 abstract "It has been established that an electron-deficient CpRhIII complex, bearing two ester moieties on the Cp ring, [CpERhIII], catalyzes the aerobic oxidative cross coupling of substituted acrylamides with both activated and unactivated alkenes, leading to (2Z,4E)-dienamides, at relatively low temperature (80 °C). Importantly, tertiary, secondary, and primary amide directing groups could equally be used in this catalysis. The mechanistic studies revealed that the electron-deficient nature of the CpERhIII complex facilitates the turnover-limiting vinylic C-H bond cleavage of the acrylamides." @default.
• W2969014695 created "2019-08-22" @default.
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• W2969014695 date "2019-08-16" @default.
• W2969014695 modified "2023-09-24" @default.
• W2969014695 title "Aerobic Oxidative Cross-Coupling of Substituted Acrylamides with Alkenes Catalyzed by an Electron-Deficient CpRh^III Complex" @default.
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• W2969014695 doi "https://doi.org/10.1021/acs.joc.9b01733" @default.
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