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- W2969096875 abstract "1,3-Bis(dicyanomethylidene)indan anion (CMI–) is a stable π-electronic anion prepared by self-deprotonation. A series of ion-pairing assemblies based on CMI– were investigated by various π-electronic cations. The packing structures were revealed by single-crystal X-ray analysis, and charge-by-charge and charge-segregated assemblies were obtained. Interestingly, cation–cation and/or anion–anion stacking formations were observed in all the crystal structures, although electrostatic repulsion effects exist between identically charged species. The stabilization of the identically charged stackings by the dipole–dipole interactions was explained from the DFT calculations. In addition, the delocalization of negative or positive charge through the face-to-face stacking and hydrogen bonding between the differently charged species also play an important role for the formation of various assemblies." @default.
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- W2969096875 date "2019-08-16" @default.
- W2969096875 modified "2023-10-17" @default.
- W2969096875 title "Various Ionic Crystals from the Combination of 1,3-Bis(dicyanomethylidene)indan Anion and π-Electronic Cations" @default.
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- W2969096875 doi "https://doi.org/10.1021/acs.cgd.9b00841" @default.
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