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- W2969162328 abstract "High-quality low-dimensional polymer synthesis is a promising route to fabricating high-performance functional nanomaterials. The Ullmann is a frequently-employed with the drawback of unwanted metal-halide byproducts. This project investigates two approaches for the formation of byproduct-free ordered polymers: (a) employing decarboxylation coupling as a clean reaction and (b) removal of the metal-halide byproduct by etching with a beam of atomic hydrogen after Ullmann coupling. Both approaches provide new insight into molecule–substrate interactions, intermolecular interactions and the halogen's effect on the polymerization and products." @default.
- W2969162328 created "2019-08-22" @default.
- W2969162328 creator A5091003334 @default.
- W2969162328 date "2019-07-09" @default.
- W2969162328 modified "2023-09-23" @default.
- W2969162328 title "Molecular Reactions on Surfaces: Towards the Growth of Surface-Confined Polymers" @default.
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- W2969162328 doi "https://doi.org/10.5204/thesis.eprints.130754" @default.
- W2969162328 hasPublicationYear "2019" @default.
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