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- W2969190099 abstract "We report a new water-stable multivariate (MTV) metal-organic framework (MOF) prepared by combining two different oxamide-based metalloligands derived from the natural amino acids l-serine and l-methionine. This unique material features hexagonal channels decorated with two types of flexible and functional arms (-CH2OH and -CH2CH2SCH3) capable of enabling, synergistically, the simultaneous and efficient removal of both inorganic (heavy metals such as Hg2+, Pb2+, and Tl+) and organic (dyes such as Pyronin Y, Auramine O, Brilliant green, and Methylene blue) contaminants, and, in addition, this MTV-MOF is completely reusable. Single-crystal X-ray diffraction measurements allowed solving the crystal structure of a host-guest adsorbate, containing both HgCl2 and Methylene blue, and offered unprecedented snapshots of this unique dual capture process. This is the very first time that a MOF can be used for the removal of all sorts of pollutants from water resources, thus opening new perspectives for this emerging type of MTV-MOF." @default.
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- W2969190099 date "2019-08-08" @default.
- W2969190099 modified "2023-10-17" @default.
- W2969190099 title "Multivariate Metal–Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water" @default.
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- W2969190099 doi "https://doi.org/10.1021/jacs.9b06250" @default.
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