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- W2969260028 endingPage "130540" @default.
- W2969260028 startingPage "130540" @default.
- W2969260028 abstract "Abstract A convenient and environmental benign synthesis of biaryls has been demonstrated by a straightforward reaction catalyzed by the palladium-containing metal-organic framework (Pd-MOF) [Pd (2-pymo)2]n (2-pymo = 2-pyrimidinolate). A series of functionalized biaryl derivatives have been synthesized in good to excellent yields by the Suzuki-miyaura cross-couplings of sustainable arenediazonium salts with a variety of arylboronic acids and the reactions were catalyzed by the Pd-MOF using methanol as a benign solvent. Those base- and additive-free catalytic reactions proceeded smoothly under non-anhydrous and non-degassed condition. Such transformation avoided high reaction temperature, tolerated many functional groups and presented a wide substrate scope. The catalyst could be recovered by filtration and reused for four successive cycles before collapse of the MOF structure." @default.
- W2969260028 created "2019-08-29" @default.
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- W2969260028 date "2019-10-01" @default.
- W2969260028 modified "2023-10-15" @default.
- W2969260028 title "Base-free Pd-MOF catalyzed the Suzuki-Miyaura cross-coupling reaction of arenediazonium tetrafluoroborate salts with arylboronic acids" @default.
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- W2969260028 doi "https://doi.org/10.1016/j.tet.2019.130540" @default.
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