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- W2969277517 endingPage "101" @default.
- W2969277517 startingPage "67" @default.
- W2969277517 abstract "Beyond organic electronics, fluoropolymers are now investigated for many applications such as biomedical, energy harvesting due to their piezoelectric and ferroelectric properties, their flexible and stretchable features, and the easiness to prepare micro-nanostructures. PVDF has the simplest repeat unit and is much studied because of its five polymorphs obtained by different processing methods. Alpha, beta, and gamma phases are mainly investigated. Beta and gamma phases are the most electroactive and are leading to extensive applications, while alpha is the easiest phase to be obtained. Even nonpolar, alpha is very interesting to carry out alpha-to-beta transformation by stretching. The crystallization of beta polymorph can also be induced by the introduction of nanofillers that present the interest to create a synergy between the properties of the fillers and the matrix. Therefore, the advent of the “nano” has contributed to a revival of the PVDF. Combining the properties of several components at multiple scales allows the development of hierarchically structured and multifunctional composites. The purpose of this state of the art on fluoropolymer-based hybrid films is, first, to describe the basics on PVDF. Among all PVDF-based copolymers, PVDF is chosen as the simplest structure and a simple model for presenting a methodology for the synthesis and characterization of such hybrid materials. Part I is describing the processing and characterizations of self-standing and flexible PVDF films. Then, part II is developing the state of the art on flexible PVDF-based hybrid films focusing on magnetoelectric materials, in which the size, the shape and the surface functionalization of ferrite nanoparticles (NPs) have an influence on the resulting morphology and properties. Hence, this discussion can be transposed to other nanocomposites. In part III, some conclusions on the influence of the size and the shape of the NPs on the crystallization of beta phase are presented." @default.
- W2969277517 created "2019-08-29" @default.
- W2969277517 creator A5031282869 @default.
- W2969277517 date "2019-01-01" @default.
- W2969277517 modified "2023-10-17" @default.
- W2969277517 title "Nanostructured flexible PVDF and fluoropolymer-based hybrid films" @default.
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