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- W2969296814 abstract "Currently, cobalt monoxide (CoO) has received considerable attention because of its promising applications for lithium-ion batteries (LIBs). However, nanostructured CoO anode materials still suffer from poor conductivity and large volume changes. Solving these obstacles is essential to gain maximum lithium storage efficiencies. Herein, we present three-dimensional structured nanofibrous SiOx/C/CoO composites by using a low-cost and practical liquid-phase deposition method with subsequent thermal treatment. Further studies indicate that additional oxygen vacancies were generated and activated oxygen from the oxygen defect reacted with cobalt ions to form CoO. A uniform Co-MOF derivative shell coated on silica nanofiber core is observed to have a high lithium diffusion coefficient, surface-capacitive effect, and excellent structural stability. As a result, nanofibrous SiOx/C/CoO exhibits excellent lithium storage performance, including a high discharge capacity of 753.6 mA h g−1 at 0.1 A g−1, excellent retention of 83.8% after 120 cycles, satisfactory rate capacity of 369.9 mA h g−1 at 2 A g−1, and long-term cyclic stability of up to 600 cycles at 0.5 A g−1 for LIBs." @default.
- W2969296814 created "2019-08-29" @default.
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- W2969296814 date "2019-11-01" @default.
- W2969296814 modified "2023-10-03" @default.
- W2969296814 title "Fabrication of nanofibrous SiO /C/CoO composites with fast reaction kinetic and excellent structural stability for lithium storage" @default.
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- W2969296814 doi "https://doi.org/10.1016/j.jallcom.2019.151971" @default.
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