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• W2969338553 abstract "Epitaxial $p$-type transparent conducting oxide (TCO) $mathrm{C}{mathrm{r}}_{2}{mathrm{O}}_{3}:mathrm{Mg}$ was grown by electron-beam evaporation in a molecular beam epitaxy system on $c$-plane sapphire. The influence of Mg dopants and the oxygen partial pressure were investigated by thermoelectric and electrical measurements. The conduction mechanism is analyzed using the small-polaron hopping model, and hopping activation energies have been determined, which vary with doping concentration in the range of 210--300 ifmmodepmelsetextpmfi{} 5 meV. Films with better conductivity were obtained by postannealing. The effect of postannealing is discussed in terms of a crystallographic reordering of the Mg dopant. The highest Seebeck mobilities obtained from thermoelectric measurements are of the order of ${10}^{ensuremath{-}4}phantom{rule{0.16em}{0ex}}{mathrm{cm}}^{2}{mathrm{V}}^{ensuremath{-}1}{mathrm{s}}^{ensuremath{-}1}$. We investigate the fundamental properties of a Mg dopant in a high crystalline quality epitaxial film of a binary oxide, helping us understand the role of short range crystallographic order in a $p$-type TCO in detail." @default.
• W2969338553 created "2019-08-29" @default.
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• W2969338553 date "2015-03-02" @default.
• W2969338553 modified "2023-10-08" @default.
• W2969338553 title "Conducting mechanism in the epitaxial<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mi>p</mml:mi></mml:math>-type transparent conducting oxide<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi mathvariant=normal>C</mml:mi><mml:msub><mml:mi mathvariant=normal>r</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>:</mml:mo><mml:mi>Mg</mml:mi></mml:mrow></mml:math>" @default.
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• W2969338553 doi "https://doi.org/10.1103/physrevb.91.125202" @default.
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