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- W2969351380 abstract "Selective intramolecular aldol condensation of 2,5-hexanedione (HD), which is producible from 5-hydroxymethyl-2-furaldehyde (HMF) via hydrogenolysis and successive hydrolysis, towards 3-methyl-2-cyclopentenone (MCP) is examined with various solid acid catalysts. It is found out that the simple aluminum oxides such as γ-Al2O3 and AlOOH gave an attractive performance for the MCP generation from HD with high selectivity (>71%). After the hydrothermal treatment for 6 h on γ-Al2O3 to modify its acidity, it is found that as-prepared γ-Al2O3/AlOOH nanocomposite exhibits the yield of 77.2% with the highest selectivity of 85.9% for MCP." @default.
- W2969351380 created "2019-08-29" @default.
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- W2969351380 date "2019-12-01" @default.
- W2969351380 modified "2023-10-10" @default.
- W2969351380 title "Selective synthesis of 3-methyl-2-cyclopentenone via intramolecular aldol condensation of 2,5-hexanedione with γ-Al2O3/AlOOH nanocomposite catalyst" @default.
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- W2969351380 doi "https://doi.org/10.1016/j.fuproc.2019.106185" @default.
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