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- W2969492715 abstract "A photoredox benzyl activation was developed via formidable C(sp 3 )–C(sp 3 ) bond dissociation of 1‐aryl acetone oxime esters, which were easily prepared from benzyl ketones. Further coupling with O‐ and N‐ nucleophiles successfully forged important benzyl ether and amines derivatives in one pot. In this process, different substitutions on oxime esters were found compatible and various primary and secondary alcohols and amines, as well as amides showed good performance as nucleophiles. Mechanistic studies by control experiments, electrochemical measurements and in‐situ NMR spectra proposed a N–O bond interruption/C–C bond fragmentation/oxidation sequence to provide the key cation intermediate for the next electrophilic S N process. The features of mild condition, short reaction time and broad substrate scope made this new strategy much promising in the transformation of benzyl compounds, which might be valuable in last‐stage functionalizations." @default.
- W2969492715 created "2019-08-29" @default.
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- W2969492715 date "2019-09-05" @default.
- W2969492715 modified "2023-10-14" @default.
- W2969492715 title "Benzyl C–O and C–N Bond Construction via C–C Bond Dissociation of Oxime Ester under Visible Light Irradiation" @default.
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- W2969492715 doi "https://doi.org/10.1002/ejoc.201901060" @default.
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