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- W2969659910 abstract "Abstract Sorptive Bioaccessibility Extraction (SBE) was used to monitor changes in accessibility of polycyclic aromatic hydrocarbons (PAHs) during storage of historically contaminated alkaline soil (Σ US EPA 16 + 2 further PAHs: 2452 ± 69 mg kg−1, n = 3). While total concentrations of PAHs were rather stable during storage for 561 days at 4 °C, PAH accessibility declined by 95% due to atmospheric carbonation. The formation of carbonates was evidenced by an increase of inorganic soil carbon and by carbonate coatings on black soil particles (SEM-EDX) that could be dissolved by providing neutral to acidic soil conditions. Subjecting soil (252 days of storage) to biodegradation at pH 7 resulted in a degraded fraction of PAHs equivalent to the accessible PAH fraction of soil as received (PAHs with log Kow" @default.
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- W2969659910 date "2020-02-01" @default.
- W2969659910 modified "2023-10-01" @default.
- W2969659910 title "Atmospheric carbonation reduces bioaccessibility of PAHs in industrially contaminated soil" @default.
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- W2969659910 doi "https://doi.org/10.1016/j.jhazmat.2019.121092" @default.
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