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- W2969687150 endingPage "113102" @default.
- W2969687150 startingPage "113102" @default.
- W2969687150 abstract "Per- and poly-fluoroalkyl substances (PFAS) have attracted considerable concern due to their widespread occurrence in the environment and potential human health risks. Given the complexity of PFAS retention in multi-phase systems, it would be useful for characterization and modeling purposes to be able to readily determine the relative significance of the individual retention processes for a given PFAS and set of subsurface conditions. A quantitative-structure/property-relationship (QSPR) analysis was conducted for adsorption of PFAS by soils, sediments, and granular activated carbon (GAC), and integrated with a prior analysis conducted for adsorption to air-water and oil-water interfaces. The results demonstrated that a model employing molar volume provided reasonable predictions of organic-carbon normalized soil/sediment adsorption coefficients (log Koc), GAC-adsorption coefficients (log Kd), and air/oil-water interfacial adsorption coefficients (log Ki) for PFAS. The relative magnitudes of solid-water and air/oil-water interfacial adsorption were compared as a function of controlling variables. A nomograph was developed that provides a first-order determination of the relative significance of these interfacial adsorption processes in multi-phase porous-media systems." @default.
- W2969687150 created "2019-08-29" @default.
- W2969687150 creator A5073561211 @default.
- W2969687150 date "2019-11-01" @default.
- W2969687150 modified "2023-10-12" @default.
- W2969687150 title "Estimating the relative magnitudes of adsorption to solid-water and air/oil-water interfaces for per- and poly-fluoroalkyl substances" @default.
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- W2969687150 doi "https://doi.org/10.1016/j.envpol.2019.113102" @default.
- W2969687150 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6800169" @default.
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