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• W2969691344 abstract "Peroxidovanadium(V) and oxidovanadium(IV) compounds have been tested as peroxidase-similar compounds. Their catalytic performance was tested on phenol red and pyrogallol substrates. Bromination kinetic studies revealed Michaelis-Menten behavior with respect to phenol red for both complexes. Catalytic efficiency is ~ 104 M−1 min−1. Both vanadium complexes showed the capacity to oxidize pyrogallol, but only the oxidovanadium (IV) complex follows Michaelis-Menten kinetics with respect to this substrate (Km = 1.05 × 10-3 M). Peroxidovanadium(V) complex displayed a more complex mechanism, and further studies became necessary to elucidate it. The structure-activity relationship was also assessed." @default.
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• W2969691344 date "2019-08-24" @default.
• W2969691344 modified "2023-10-05" @default.
• W2969691344 title "Vanadium Compounds as Biocatalyst Models" @default.
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• W2969691344 doi "https://doi.org/10.1007/s12011-019-01874-5" @default.
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