Matches in SemOpenAlex for { <https://semopenalex.org/work/W2969698910> ?p ?o ?g. }
- W2969698910 endingPage "6457" @default.
- W2969698910 startingPage "6449" @default.
- W2969698910 abstract "We report the microphase-separated morphologies of model bottlebrush block copolymers (BBCPs) over a wide range of architectural design parameters. Densely grafted polystyrene-block-poly(dimethylsiloxane) (PS-b-PDMS) BBCPs rapidly self-assemble into ordered lamellar, cylindrical, and deformed spherical morphologies depending on the volume fraction (f), side chain length (Nsc), and overall backbone length (Nbb). The microstructure was characterized by using electron microscopy and X-ray scattering. An experimental phase map is constructed, describing the dependence of morphologies and order–order transitions with respect to the design parameters. A lamellar morphology is primarily observed at symmetric f, while ordered cylindrical and deformed spherical morphologies appear at asymmetric f. The relative flexibility of the PS-b-PDMS backbone facilitates the accessibility of morphologies with curved interfaces and exceptionally large domain spacing. We also find that the breadth of the lamellar window decreases with increasing backbone length and side-chain asymmetry. These findings provide a comprehensive experimental description of the PS-b-PDMS BBCPs and provide insight into the rich phase behavior of this class of macromolecules." @default.
- W2969698910 created "2019-08-29" @default.
- W2969698910 creator A5015281820 @default.
- W2969698910 creator A5026292542 @default.
- W2969698910 creator A5035563239 @default.
- W2969698910 creator A5038476578 @default.
- W2969698910 creator A5043482216 @default.
- W2969698910 creator A5073217965 @default.
- W2969698910 date "2019-08-21" @default.
- W2969698910 modified "2023-10-15" @default.
- W2969698910 title "Influence of Molecular Architecture and Chain Flexibility on the Phase Map of Polystyrene-<i>block</i>-poly(dimethylsiloxane) Brush Block Copolymers" @default.
- W2969698910 cites W1975562526 @default.
- W2969698910 cites W1991424874 @default.
- W2969698910 cites W2022874479 @default.
- W2969698910 cites W2026132129 @default.
- W2969698910 cites W2029707199 @default.
- W2969698910 cites W2041328716 @default.
- W2969698910 cites W2057831455 @default.
- W2969698910 cites W2060015544 @default.
- W2969698910 cites W2068814171 @default.
- W2969698910 cites W2083851164 @default.
- W2969698910 cites W2087055966 @default.
- W2969698910 cites W2090784591 @default.
- W2969698910 cites W2111839013 @default.
- W2969698910 cites W2112329995 @default.
- W2969698910 cites W2117360035 @default.
- W2969698910 cites W2141471589 @default.
- W2969698910 cites W2160037102 @default.
- W2969698910 cites W2172226984 @default.
- W2969698910 cites W2181101088 @default.
- W2969698910 cites W2210440445 @default.
- W2969698910 cites W2310993694 @default.
- W2969698910 cites W2324162020 @default.
- W2969698910 cites W2326446927 @default.
- W2969698910 cites W2328434631 @default.
- W2969698910 cites W2335023422 @default.
- W2969698910 cites W2343414827 @default.
- W2969698910 cites W2416470717 @default.
- W2969698910 cites W2474833344 @default.
- W2969698910 cites W2517880700 @default.
- W2969698910 cites W2553422209 @default.
- W2969698910 cites W2561515125 @default.
- W2969698910 cites W2565800667 @default.
- W2969698910 cites W2588780497 @default.
- W2969698910 cites W2620241686 @default.
- W2969698910 cites W2623930691 @default.
- W2969698910 cites W2767671190 @default.
- W2969698910 cites W2792920956 @default.
- W2969698910 cites W2802547950 @default.
- W2969698910 cites W2803017114 @default.
- W2969698910 cites W2804716500 @default.
- W2969698910 cites W2805083352 @default.
- W2969698910 cites W2891556428 @default.
- W2969698910 cites W2936818046 @default.
- W2969698910 cites W4235024652 @default.
- W2969698910 doi "https://doi.org/10.1021/acs.macromol.9b00843" @default.
- W2969698910 hasPublicationYear "2019" @default.
- W2969698910 type Work @default.
- W2969698910 sameAs 2969698910 @default.
- W2969698910 citedByCount "34" @default.
- W2969698910 countsByYear W29696989102019 @default.
- W2969698910 countsByYear W29696989102020 @default.
- W2969698910 countsByYear W29696989102021 @default.
- W2969698910 countsByYear W29696989102022 @default.
- W2969698910 countsByYear W29696989102023 @default.
- W2969698910 crossrefType "journal-article" @default.
- W2969698910 hasAuthorship W2969698910A5015281820 @default.
- W2969698910 hasAuthorship W2969698910A5026292542 @default.
- W2969698910 hasAuthorship W2969698910A5035563239 @default.
- W2969698910 hasAuthorship W2969698910A5038476578 @default.
- W2969698910 hasAuthorship W2969698910A5043482216 @default.
- W2969698910 hasAuthorship W2969698910A5073217965 @default.
- W2969698910 hasConcept C15920480 @default.
- W2969698910 hasConcept C159467904 @default.
- W2969698910 hasConcept C159985019 @default.
- W2969698910 hasConcept C177418412 @default.
- W2969698910 hasConcept C178790620 @default.
- W2969698910 hasConcept C185592680 @default.
- W2969698910 hasConcept C188027245 @default.
- W2969698910 hasConcept C192562407 @default.
- W2969698910 hasConcept C204921945 @default.
- W2969698910 hasConcept C2777922577 @default.
- W2969698910 hasConcept C44280652 @default.
- W2969698910 hasConcept C45594756 @default.
- W2969698910 hasConcept C499950583 @default.
- W2969698910 hasConcept C521977710 @default.
- W2969698910 hasConcept C54355233 @default.
- W2969698910 hasConcept C77851909 @default.
- W2969698910 hasConcept C8010536 @default.
- W2969698910 hasConcept C86803240 @default.
- W2969698910 hasConceptScore W2969698910C15920480 @default.
- W2969698910 hasConceptScore W2969698910C159467904 @default.
- W2969698910 hasConceptScore W2969698910C159985019 @default.
- W2969698910 hasConceptScore W2969698910C177418412 @default.
- W2969698910 hasConceptScore W2969698910C178790620 @default.
- W2969698910 hasConceptScore W2969698910C185592680 @default.
- W2969698910 hasConceptScore W2969698910C188027245 @default.
- W2969698910 hasConceptScore W2969698910C192562407 @default.