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- W2969856757 abstract "Axially chiral 1,3-disubstituted allenes were synthesized via hydroalkylation of alkyl- or aryl-substituted conjugated enynes (readily prepared via a Sonogashira reaction) with pronucleophiles such as dimethyl malonate under the cocatalysis of DTBM-SEGPHOS-ligated palladium and lithium iodide. Although the palladium catalyst ligated with (S)-DTBM-SEGPHOS prefers the formation of (R)-1,3-disubstituted allenes, lithium iodide recovers and increases the intrinsic selectivity producing (S)-allenes by promoting the isomerization of the exo-alkylidene-π-allylpalladium intermediate prior to the nucleophilic substitution step." @default.
- W2969856757 created "2019-08-29" @default.
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- W2969856757 date "2019-08-23" @default.
- W2969856757 modified "2023-10-17" @default.
- W2969856757 title "Palladium(0)–Lithium Iodide Cocatalyzed Asymmetric Hydroalkylation of Conjugated Enynes with Pronucleophiles Leading to 1,3-Disubstituted Allenes" @default.
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- W2969856757 doi "https://doi.org/10.1021/acs.orglett.9b02439" @default.
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