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• W2969890410 startingPage "4448" @default.
• W2969890410 abstract "Intramolecular addition of an O-methyl C(sp3)−H bond across a carbon-carbon double bond occurs in the iridium-catalyzed reaction of methyl 2-(propen-2-yl)phenyl ethers. The Ir/(S)-DTBM-SEGPHOS catalyst promotes the reaction efficiently in toluene at 110–135 °C to afford 3,3-dimethyl-2,3-dihydrobenzofurans. Enantioselective C(sp3)−H addition is achieved in the reaction of methyl 2-(1-siloxyethenyl)phenyl ethers, affording enantioenriched 3-hydroxy-2,3-dihydrobenzofuran derivatives with up to 96% ee." @default.
• W2969890410 created "2019-08-29" @default.
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• W2969890410 date "2019-09-03" @default.
• W2969890410 modified "2023-09-27" @default.
• W2969890410 title "Iridium‐Catalyzed C( <i>sp</i> ³ )−H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3‐Dihydrobenzofurans" @default.
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• W2969890410 doi "https://doi.org/10.1002/adsc.201900749" @default.
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