Matches in SemOpenAlex for { <https://semopenalex.org/work/W2969894015> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2969894015 abstract "By the example of 4-fluorobenzene-1-thiolate (p-FTP) films on Au(111), we show that a long-term post-preparation storage can improve significantly the quality of fluorinated aromatic self-assembled monolayers (SAMs). Whereas the freshly prepared p-FTP films exhibit a polymorphism, with a dominance of a disordered phase, the post-preparation storage triggers a gradual phase transition to a single-phase SAM of exceptional quality. This phase is characterized by the commensurate (16 × √3) structure, a molecular footprint of 23.1 A², high orientational order, and hardly perceptible borders between individual domains, with sizes exceeding 80 nm. Significantly, the phase transition is accompanied by morphological transformation of the substrate: whereas the freshly prepared films exhibit comparably large Au adatom islands, typical of aromatic SAMs, the long-storage samples rather reveal etch-pits, typical of alkanethiolate SAMs on Au(111), which generally have a high structural order immediately after the preparation. The above results suggest a deep interrelation between the structural order in the SAMs and surface morphology. A further implication is the importance of both thermodynamic and kinetic factors, a delicate interplay of which is presumably responsible for the observed evolution of p-FTP/Au in the present case." @default.
- W2969894015 created "2019-08-29" @default.
- W2969894015 creator A5015265342 @default.
- W2969894015 creator A5027626637 @default.
- W2969894015 creator A5028231114 @default.
- W2969894015 creator A5036970887 @default.
- W2969894015 creator A5057278635 @default.
- W2969894015 creator A5059231070 @default.
- W2969894015 creator A5077950297 @default.
- W2969894015 date "2019-01-01" @default.
- W2969894015 modified "2023-09-24" @default.
- W2969894015 title "Importance of Long-Term Storage for Fluorine-Substituted Aromatic Self-Assembled Monolayers by the Example of 4-Fluorobenzene-1-Thiolate Films on Au(111)" @default.
- W2969894015 hasPublicationYear "2019" @default.
- W2969894015 type Work @default.
- W2969894015 sameAs 2969894015 @default.
- W2969894015 citedByCount "0" @default.
- W2969894015 crossrefType "journal-article" @default.
- W2969894015 hasAuthorship W2969894015A5015265342 @default.
- W2969894015 hasAuthorship W2969894015A5027626637 @default.
- W2969894015 hasAuthorship W2969894015A5028231114 @default.
- W2969894015 hasAuthorship W2969894015A5036970887 @default.
- W2969894015 hasAuthorship W2969894015A5057278635 @default.
- W2969894015 hasAuthorship W2969894015A5059231070 @default.
- W2969894015 hasAuthorship W2969894015A5077950297 @default.
- W2969894015 hasConcept C121332964 @default.
- W2969894015 hasConcept C127413603 @default.
- W2969894015 hasConcept C149288129 @default.
- W2969894015 hasConcept C159467904 @default.
- W2969894015 hasConcept C178790620 @default.
- W2969894015 hasConcept C185592680 @default.
- W2969894015 hasConcept C2776812669 @default.
- W2969894015 hasConcept C2777691172 @default.
- W2969894015 hasConcept C42360764 @default.
- W2969894015 hasConcept C44280652 @default.
- W2969894015 hasConcept C55493867 @default.
- W2969894015 hasConcept C7070889 @default.
- W2969894015 hasConcept C8010536 @default.
- W2969894015 hasConcept C97355855 @default.
- W2969894015 hasConceptScore W2969894015C121332964 @default.
- W2969894015 hasConceptScore W2969894015C127413603 @default.
- W2969894015 hasConceptScore W2969894015C149288129 @default.
- W2969894015 hasConceptScore W2969894015C159467904 @default.
- W2969894015 hasConceptScore W2969894015C178790620 @default.
- W2969894015 hasConceptScore W2969894015C185592680 @default.
- W2969894015 hasConceptScore W2969894015C2776812669 @default.
- W2969894015 hasConceptScore W2969894015C2777691172 @default.
- W2969894015 hasConceptScore W2969894015C42360764 @default.
- W2969894015 hasConceptScore W2969894015C44280652 @default.
- W2969894015 hasConceptScore W2969894015C55493867 @default.
- W2969894015 hasConceptScore W2969894015C7070889 @default.
- W2969894015 hasConceptScore W2969894015C8010536 @default.
- W2969894015 hasConceptScore W2969894015C97355855 @default.
- W2969894015 hasLocation W29698940151 @default.
- W2969894015 hasOpenAccess W2969894015 @default.
- W2969894015 hasPrimaryLocation W29698940151 @default.
- W2969894015 hasRelatedWork W1976815878 @default.
- W2969894015 hasRelatedWork W1976859710 @default.
- W2969894015 hasRelatedWork W1995128865 @default.
- W2969894015 hasRelatedWork W2000506631 @default.
- W2969894015 hasRelatedWork W2003924208 @default.
- W2969894015 hasRelatedWork W2013026314 @default.
- W2969894015 hasRelatedWork W2048810271 @default.
- W2969894015 hasRelatedWork W2075588373 @default.
- W2969894015 hasRelatedWork W2088453677 @default.
- W2969894015 hasRelatedWork W2138552862 @default.
- W2969894015 hasRelatedWork W2148525600 @default.
- W2969894015 hasRelatedWork W2183017703 @default.
- W2969894015 hasRelatedWork W2187946378 @default.
- W2969894015 hasRelatedWork W2316099730 @default.
- W2969894015 hasRelatedWork W2325256387 @default.
- W2969894015 hasRelatedWork W2327934928 @default.
- W2969894015 hasRelatedWork W2473500031 @default.
- W2969894015 hasRelatedWork W3017913803 @default.
- W2969894015 hasRelatedWork W3019050509 @default.
- W2969894015 hasRelatedWork W911157279 @default.
- W2969894015 isParatext "false" @default.
- W2969894015 isRetracted "false" @default.
- W2969894015 magId "2969894015" @default.
- W2969894015 workType "article" @default.