FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2970000658> ?p ?o ?g. }

• W2970000658 endingPage "7769" @default.
• W2970000658 startingPage "7761" @default.
• W2970000658 abstract "A detailed investigation into the synthesis of green-emitting powders of Cs4PbBr6 and CsPbBr3 materials by antisolvent precipitation from CsBr–PbBr2 precursor solutions in dimethylformamide (DMF) and dimethyl sulfoxide (DMSO) is reported. Various solvated lead bromide and polybromide species (PbBr2, [PbBr3]−, [PbBr4]2–, and possibly [PbBr5]3– or [PbBr6]4–) are detected in the precursor solutions by optical absorbance and emission spectroscopies. The solvodynamic size of the species in solution is strongly solvent-dependent: ∼1 nm species were detected in DMSO, while significantly larger species were observed in DMF by dynamic light scattering. The solvodynamic size of the lead bromide species plays a critical role in determining the Cs-Pb-Br composition of the precipitated powders: smaller species favor the precipitation of Cs4PbBr6, while larger species template the formation of CsPbBr3 under identical experimental conditions. The powders have been characterized by 133Cs and 207Pb solid-state nuclear magnetic resonance, and 133Cs sensitivity toward the different Cs environments within Cs4PbBr6 is demonstrated. Finally, the possible origins of green emission in Cs4PbBr6 samples are discussed. It is proposed that a two-dimensional Cs2PbBr4 inclusion may be responsible for green emission at ∼520 nm in addition to the widely acknowledged CsPbBr3 impurity, although we found no conclusive experimental evidence supporting such claims." @default.
• W2970000658 created "2019-09-05" @default.
• W2970000658 creator A5001294826 @default.
• W2970000658 creator A5004029612 @default.
• W2970000658 creator A5009541396 @default.
• W2970000658 creator A5013512869 @default.
• W2970000658 creator A5025956413 @default.
• W2970000658 creator A5053444612 @default.
• W2970000658 creator A5059106273 @default.
• W2970000658 creator A5061411871 @default.
• W2970000658 creator A5077883331 @default.
• W2970000658 creator A5090091915 @default.
• W2970000658 date "2019-08-28" @default.
• W2970000658 modified "2023-09-30" @default.
• W2970000658 title "Green-Emitting Powders of Zero-Dimensional Cs₄PbBr₆: Delineating the Intricacies of the Synthesis and the Origin of Photoluminescence" @default.
• W2970000658 cites W1545379950 @default.
• W2970000658 cites W1664975537 @default.
• W2970000658 cites W2003046453 @default.
• W2970000658 cites W2014446770 @default.
• W2970000658 cites W2047963521 @default.
• W2970000658 cites W2060387532 @default.
• W2970000658 cites W2084082238 @default.
• W2970000658 cites W2195844396 @default.
• W2970000658 cites W2215976296 @default.
• W2970000658 cites W2234840552 @default.
• W2970000658 cites W2291024088 @default.
• W2970000658 cites W2308354601 @default.
• W2970000658 cites W2338353692 @default.
• W2970000658 cites W2344008516 @default.
• W2970000658 cites W2400081589 @default.
• W2970000658 cites W2460326570 @default.
• W2970000658 cites W2475364504 @default.
• W2970000658 cites W2486086111 @default.
• W2970000658 cites W2511857251 @default.
• W2970000658 cites W2519673989 @default.
• W2970000658 cites W2565029499 @default.
• W2970000658 cites W2565668905 @default.
• W2970000658 cites W2569813379 @default.
• W2970000658 cites W2569826227 @default.
• W2970000658 cites W2587159679 @default.
• W2970000658 cites W2587918099 @default.
• W2970000658 cites W2591844520 @default.
• W2970000658 cites W2594550393 @default.
• W2970000658 cites W2598461673 @default.
• W2970000658 cites W2603505833 @default.
• W2970000658 cites W2618505131 @default.
• W2970000658 cites W2729297634 @default.
• W2970000658 cites W2741687969 @default.
• W2970000658 cites W2744703988 @default.
• W2970000658 cites W2752315543 @default.
• W2970000658 cites W2763531066 @default.
• W2970000658 cites W2766286939 @default.
• W2970000658 cites W2766625136 @default.
• W2970000658 cites W2767389024 @default.
• W2970000658 cites W2767705834 @default.
• W2970000658 cites W2768667191 @default.
• W2970000658 cites W2770413462 @default.
• W2970000658 cites W2781465247 @default.
• W2970000658 cites W2787179633 @default.
• W2970000658 cites W2789892453 @default.
• W2970000658 cites W2791497152 @default.
• W2970000658 cites W2792320479 @default.
• W2970000658 cites W2796834300 @default.
• W2970000658 cites W2800015877 @default.
• W2970000658 cites W2810997483 @default.
• W2970000658 cites W2887793887 @default.
• W2970000658 cites W2887976745 @default.
• W2970000658 cites W2890866930 @default.
• W2970000658 cites W2897552127 @default.
• W2970000658 cites W2901657000 @default.
• W2970000658 cites W2911829025 @default.
• W2970000658 cites W2912276284 @default.
• W2970000658 cites W4248297893 @default.
• W2970000658 doi "https://doi.org/10.1021/acs.chemmater.9b02944" @default.
• W2970000658 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7116092" @default.
• W2970000658 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32952293" @default.
• W2970000658 hasPublicationYear "2019" @default.
• W2970000658 type Work @default.
• W2970000658 sameAs 2970000658 @default.
• W2970000658 citedByCount "58" @default.
• W2970000658 countsByYear W29700006582019 @default.
• W2970000658 countsByYear W29700006582020 @default.
• W2970000658 countsByYear W29700006582021 @default.
• W2970000658 countsByYear W29700006582022 @default.
• W2970000658 countsByYear W29700006582023 @default.
• W2970000658 crossrefType "journal-article" @default.
• W2970000658 hasAuthorship W2970000658A5001294826 @default.
• W2970000658 hasAuthorship W2970000658A5004029612 @default.
• W2970000658 hasAuthorship W2970000658A5009541396 @default.
• W2970000658 hasAuthorship W2970000658A5013512869 @default.
• W2970000658 hasAuthorship W2970000658A5025956413 @default.
• W2970000658 hasAuthorship W2970000658A5053444612 @default.
• W2970000658 hasAuthorship W2970000658A5059106273 @default.
• W2970000658 hasAuthorship W2970000658A5061411871 @default.
• W2970000658 hasAuthorship W2970000658A5077883331 @default.
• W2970000658 hasAuthorship W2970000658A5090091915 @default.
• W2970000658 hasBestOaLocation W29700006581 @default.
• W2970000658 hasConcept C107054158 @default.

• next