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- W2970051550 endingPage "633" @default.
- W2970051550 startingPage "620" @default.
- W2970051550 abstract "Abstract The treatment of toxic and difficult-to-degrade phenolic compounds has become a key issue in the coking, pharmaceutical, and chemical industries. Considering the polymerization and oxidation of phenolic compounds in supercritical water partial oxidation/supercritical water oxidation (SCWPO/SCWO), the present study reviewed the removal efficiency and reaction pathway of phenolic compounds and phenolic waste/wastewater under different reaction conditions. Temperature is the dominant factor affecting the SCWO reaction. When the oxidizing ability is insufficient, the organics polymerize to form phenolic compounds. The gradual increase of oxidant equivalent causes the intermediate product to gradually oxidize to CO2 and H2O completely. Finally, the free radical reaction mechanism is considered to be a typical SCWO reaction mechanism." @default.
- W2970051550 created "2019-09-05" @default.
- W2970051550 creator A5003047436 @default.
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- W2970051550 creator A5055220587 @default.
- W2970051550 creator A5075399400 @default.
- W2970051550 creator A5079382582 @default.
- W2970051550 date "2019-08-15" @default.
- W2970051550 modified "2023-09-27" @default.
- W2970051550 title "Polymerization and oxidation of phenols in supercritical water" @default.
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- W2970051550 doi "https://doi.org/10.2166/wst.2019.295" @default.