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• W2970117252 endingPage "114129" @default.
• W2970117252 startingPage "114129" @default.
• W2970117252 abstract "We have synthesized three octahedral Co(III) compounds in order to study their catalytic efficiency for the oxidation of 3,5-di-tertiarybutylcatechol (3,5-DTBC) into the corresponding quinone. Among the tested compounds, only one compound, 3 shows the catecholase activity. The catalytic efficiency of this compound arises from its capability to stabilise two different oxidation states of the metal centre. The initial oxidation state of cobalt ion (Co(III)) changes into Co(II) in order to accommodate the substrate. The kinetic parameters were calculated using the Michaelis-Menten equation. The catalytic loop was proposed and the byproduct formed in the cycle was experimentally determined." @default.
• W2970117252 created "2019-09-05" @default.
• W2970117252 creator A5029184542 @default.
• W2970117252 creator A5043735913 @default.
• W2970117252 date "2019-11-01" @default.
• W2970117252 modified "2023-10-10" @default.
• W2970117252 title "Investigation on catecholase activity of salen Co(III) octahedral complexes" @default.
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• W2970117252 doi "https://doi.org/10.1016/j.poly.2019.114129" @default.
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