Matches in SemOpenAlex for { <https://semopenalex.org/work/W2970223286> ?p ?o ?g. }
- W2970223286 endingPage "14047" @default.
- W2970223286 startingPage "14042" @default.
- W2970223286 abstract "Abstract The use of the electrostatic stoppers concept in the field of mechanically interlocked molecules is reported; these stoppers are chemically sensitive end groups on a linear guest molecule that allows for the conversion of a pseudo ‐rotaxane species into a rotaxane complex by a change in the medium acidity. The chemical stimulus causes the appearance of negative charges on both ends of the linear component, passing from cationic to anionic, and causing a significant ring‐to‐axle electrostatic repulsion. This phenomenon has two different and simultaneous effects: 1) destabilizes the complex as a consequence of confining an anionic ring into an anionic axle, and 2) increases the dissociation energy barrier, thus impeding ring extrusion. This newly formed metastable rotaxane species is resistant to solvent and temperature effects and performs as a two‐state degenerated molecular shuttle in solution." @default.
- W2970223286 created "2019-09-05" @default.
- W2970223286 creator A5006319926 @default.
- W2970223286 creator A5014314980 @default.
- W2970223286 creator A5020132171 @default.
- W2970223286 creator A5064340804 @default.
- W2970223286 creator A5080405945 @default.
- W2970223286 date "2019-10-18" @default.
- W2970223286 modified "2023-10-11" @default.
- W2970223286 title "An Anionic Ring Locked into an Anionic Axle: A Metastable Rotaxane with Chemically Activated Electrostatic Stoppers" @default.
- W2970223286 cites W1458390031 @default.
- W2970223286 cites W1497035718 @default.
- W2970223286 cites W1963971799 @default.
- W2970223286 cites W1964287840 @default.
- W2970223286 cites W1968697486 @default.
- W2970223286 cites W1980113383 @default.
- W2970223286 cites W1980822803 @default.
- W2970223286 cites W1983915778 @default.
- W2970223286 cites W1994449387 @default.
- W2970223286 cites W1998258065 @default.
- W2970223286 cites W2010137260 @default.
- W2970223286 cites W2015001791 @default.
- W2970223286 cites W2028145097 @default.
- W2970223286 cites W2031400043 @default.
- W2970223286 cites W2044496967 @default.
- W2970223286 cites W2059678919 @default.
- W2970223286 cites W2060953412 @default.
- W2970223286 cites W2065874146 @default.
- W2970223286 cites W2088810112 @default.
- W2970223286 cites W2089485110 @default.
- W2970223286 cites W2092054921 @default.
- W2970223286 cites W2106419217 @default.
- W2970223286 cites W2107031766 @default.
- W2970223286 cites W2169264475 @default.
- W2970223286 cites W2301373502 @default.
- W2970223286 cites W2323842433 @default.
- W2970223286 cites W2331324928 @default.
- W2970223286 cites W2432301401 @default.
- W2970223286 cites W2536076933 @default.
- W2970223286 cites W2642974867 @default.
- W2970223286 cites W2681634415 @default.
- W2970223286 cites W2741589538 @default.
- W2970223286 cites W2746171221 @default.
- W2970223286 cites W2749358101 @default.
- W2970223286 cites W2765491844 @default.
- W2970223286 cites W2886575438 @default.
- W2970223286 cites W4205339990 @default.
- W2970223286 cites W4244573159 @default.
- W2970223286 cites W653382042 @default.
- W2970223286 doi "https://doi.org/10.1002/chem.201902735" @default.
- W2970223286 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31468580" @default.
- W2970223286 hasPublicationYear "2019" @default.
- W2970223286 type Work @default.
- W2970223286 sameAs 2970223286 @default.
- W2970223286 citedByCount "3" @default.
- W2970223286 countsByYear W29702232862021 @default.
- W2970223286 countsByYear W29702232862022 @default.
- W2970223286 crossrefType "journal-article" @default.
- W2970223286 hasAuthorship W2970223286A5006319926 @default.
- W2970223286 hasAuthorship W2970223286A5014314980 @default.
- W2970223286 hasAuthorship W2970223286A5020132171 @default.
- W2970223286 hasAuthorship W2970223286A5064340804 @default.
- W2970223286 hasAuthorship W2970223286A5080405945 @default.
- W2970223286 hasConcept C102931765 @default.
- W2970223286 hasConcept C117626034 @default.
- W2970223286 hasConcept C121897927 @default.
- W2970223286 hasConcept C127413603 @default.
- W2970223286 hasConcept C129727815 @default.
- W2970223286 hasConcept C147789679 @default.
- W2970223286 hasConcept C159467904 @default.
- W2970223286 hasConcept C178790620 @default.
- W2970223286 hasConcept C183882617 @default.
- W2970223286 hasConcept C185592680 @default.
- W2970223286 hasConcept C188027245 @default.
- W2970223286 hasConcept C192562407 @default.
- W2970223286 hasConcept C2780378348 @default.
- W2970223286 hasConcept C32909587 @default.
- W2970223286 hasConcept C75473681 @default.
- W2970223286 hasConcept C78519656 @default.
- W2970223286 hasConcept C89464430 @default.
- W2970223286 hasConcept C93275456 @default.
- W2970223286 hasConceptScore W2970223286C102931765 @default.
- W2970223286 hasConceptScore W2970223286C117626034 @default.
- W2970223286 hasConceptScore W2970223286C121897927 @default.
- W2970223286 hasConceptScore W2970223286C127413603 @default.
- W2970223286 hasConceptScore W2970223286C129727815 @default.
- W2970223286 hasConceptScore W2970223286C147789679 @default.
- W2970223286 hasConceptScore W2970223286C159467904 @default.
- W2970223286 hasConceptScore W2970223286C178790620 @default.
- W2970223286 hasConceptScore W2970223286C183882617 @default.
- W2970223286 hasConceptScore W2970223286C185592680 @default.
- W2970223286 hasConceptScore W2970223286C188027245 @default.
- W2970223286 hasConceptScore W2970223286C192562407 @default.
- W2970223286 hasConceptScore W2970223286C2780378348 @default.
- W2970223286 hasConceptScore W2970223286C32909587 @default.
- W2970223286 hasConceptScore W2970223286C75473681 @default.
- W2970223286 hasConceptScore W2970223286C78519656 @default.
- W2970223286 hasConceptScore W2970223286C89464430 @default.