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• W2970359518 startingPage "100502" @default.
• W2970359518 abstract "Solution V, Nb K-edge XANES (X-ray absorption near edge structure) analysis of molecular catalysis, high oxidation state vanadium(V), niobium(V) complexes containing both imido ligands (possessing metal–nitrogen double bond, NR) and mono anionic ancillary donor ligands (L) of type, M(NR)(L)X2 (X = Cl, Me), which catalyze ethylene dimerization/polymerization in the presence of Al cocatalysts, has been explored. The analysis method is highly useful to obtain the direct information of the active species (oxidation state, basic framework around the centered metal) in solution (in situ), and should thus become a powerful tool for better understanding the catalysis mechanism, basic coordination and organometallic chemistry." @default.
• W2970359518 created "2019-09-05" @default.
• W2970359518 creator A5032726806 @default.
• W2970359518 creator A5048382701 @default.
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• W2970359518 date "2019-09-26" @default.
• W2970359518 modified "2023-09-30" @default.
• W2970359518 title "Direct observation of catalytically active species in reaction solution by X-ray absorption spectroscopy (XAS)" @default.
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• W2970359518 doi "https://doi.org/10.7567/1347-4065/ab3e5c" @default.
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