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- W2970441007 abstract "Single crystals of the layered, van der Waals compound $mathrm{VB}{mathrm{r}}_{3}$ were synthesized by a vapor transport technique, and characterized by single-crystal x-ray diffraction, temperature- and field-dependent magnetization, and temperature-dependent specific-heat measurements. $mathrm{VB}{mathrm{r}}_{3}$ has a honeycomb-based $mathrm{Bi}{mathrm{I}}_{3}$-type structure with space group $Rtext{ensuremath{-}}3$ (no. 148) at 100 K, analogous to the structure of other honeycomb trihalides. Structural stacking faults were observed as evidenced by the streaking of reflections along $c*$ in the diffraction data. $mathrm{VB}{mathrm{r}}_{3}$ goes through a structural phase transition at 90.4 K and a subsequent antiferromagnetic phase transition at 26.5 K, below which the magnetic moments are primarily aligned along the $c$ axis." @default.
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- W2970441007 date "2019-08-29" @default.
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- W2970441007 title "Crystal structure and magnetic properties of the layered van der Waals compound <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi>VB</mml:mi><mml:msub><mml:mi mathvariant=normal>r</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>" @default.
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