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• W2970487523 abstract "Abstract In this study, a newly isolated strain screened from the indoxacarb‐rich agricultural soils, Bacillus cereus WZZ006, has a high stereoselectivity to racemic substrate 5‐chloro‐1‐oxo‐2,3‐dihydro‐2‐hydroxy‐1 H ‐indene‐2‐carboxylic acid methyl ester. ( S )‐5‐chloro‐1‐oxo‐2,3‐dihydro‐2‐hydroxy‐1 H ‐indene‐2‐carboxylic acid methyl ester was obtained by bio‐enzymatic resolution. After the 36‐hour hydrolysis in 50‐mM racemic substrate under the optimized reaction conditions, the e.e . s was up to 93.0% and the conversion was nearly 53.0% with the E being 35.0. Therefore, B cereus WZZ006 performed high‐level ability to produce ( S )‐5‐chloro‐1‐oxo‐2,3‐dihydro‐2‐hydroxy‐1 H ‐indene‐2‐carboxylic acid methyl ester. This study demonstrates a new biocatalytic process route for preparing the indoxacarb chiral intermediates and provides a theoretical basis for the application of new insecticides in agricultural production." @default.
• W2970487523 created "2019-09-05" @default.
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• W2970487523 date "2019-08-29" @default.
• W2970487523 modified "2023-09-28" @default.
• W2970487523 title "Whole‐cell biocatalytic of<i>Bacillus cereus</i>WZZ006 strain to synthesis of indoxacarb intermediate: (<i>S</i>)‐5‐Chloro‐1‐oxo‐2,3‐dihydro‐2‐hydroxy‐1<i>H</i>‐indene‐2‐carboxylic acid methyl ester" @default.
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• W2970487523 doi "https://doi.org/10.1002/chir.23124" @default.
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• W2970487523 hasPublicationYear "2019" @default.
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