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- W2970574347 abstract "A coumarin–tetrapeptide conjugate, EFEK(DAC)–NH2 (1), is reported to undergo a pH-dependent interconversion between nanotubes and nanoribbons. An examination of zeta potential measurements, circular dichroism (CD) spectra, and microscopy imaging (transmission electron microscopy and atomic force microscopy) identified three different self-assembly regimes based on pH: (1) pH 2–5, positively charged, left-handed helical nanotubes; (2) pH 6–8, negatively charged, right-handed helical nanoribbons; and (3) pH ≥ 9.0, a monomeric/disassembled peptide. The nanotubes exhibited uniform diameters of 41 ± 5 nm and wall thicknesses of 4.8 ± 0.8 nm, whereas the nanoribbons existed as either flat or twisted sheets ranging in width from 11 to 60 nm with heights of 8 ± 1 nm. The UV–vis and CD spectra of the most common antiparallel, β-sheet conformation of 1-dimer were simulated at the B3LYP/def2svpd level of theory in implicit water. These studies indicated that the transition from nanotubes to nanoribbons was coupled to an M → P helical inversion of the coumarin packing orientation, respectively, within the nanostructures. The assembly process was driven by β-sheet aggregation and π–π interactions, leading to the formation of nanoribbons, which progressively wound into helical ribbons and laterally grew into smooth nanotubes as the pH decreased." @default.
- W2970574347 created "2019-09-05" @default.
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- W2970574347 date "2019-08-30" @default.
- W2970574347 modified "2023-10-18" @default.
- W2970574347 title "pH-Controlled Chiral Packing and Self-Assembly of a Coumarin Tetrapeptide" @default.
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- W2970574347 doi "https://doi.org/10.1021/acs.langmuir.9b01939" @default.
- W2970574347 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31469284" @default.
- W2970574347 hasPublicationYear "2019" @default.
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