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• W2970704211 abstract "How strong are van der Waals interactions in determining the final outcome of self-assembled structures of small molecular systems? Herein we report isolable phthalocyanine (Pc) dimers bound by π-π interactions between monomeric Pcs which can be handled as single entities. Pc dimers have been continuously investigated as one of the simplest models of Pc aggregates. Pcs were substituted with eight dihydrodiazapentacene (DHDAP) moieties on the periphery, which act as pillar-like π-planes and these molecules form H-type dimers with the help of synergetic π-π interactions between two co-facial Pc rings and among the pillar-like DHDAP moieties. The dimer structures were fully confirmed by 1D and 2D NMR, ESR, and electronic absorption measurements. The dissociation of these dimers was observed in particular solvents such as o-dichlorobenzene, due to the good solubility of the larger π-conjugated molecules. On the other hand, in ethyl acetate the monomers were metastable species and underwent selective dimerization. Interestingly in THF, neither the dimerization of the monomers nor the dissociation of dimers was observed, suggesting that both the dimers and the monomers were kinetically well stabilized. For hours to days, we can handle these dimers as a molecule not only in solution but also even in mass spectrometry under ionization conditions without significant dissociation." @default.
• W2970704211 created "2019-09-05" @default.
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• W2970704211 date "2019-01-01" @default.
• W2970704211 modified "2023-10-17" @default.
• W2970704211 title "Extreme multi-point van der Waals interactions: isolable dimers of phthalocyanines substituted with pillar-like azaacenes" @default.
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• W2970704211 doi "https://doi.org/10.1039/c9sc01739a" @default.
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