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- W2970704366 endingPage "10058" @default.
- W2970704366 startingPage "10052" @default.
- W2970704366 abstract "Abstract Atomically precise enantiomeric metal clusters are scarce, and copper(I) alkynyl clusters with intense circularly polarized luminescence (CPL) responses have not been reported. A pair of chiral alkynyl ligands, (R/S)‐2‐diphenyl‐2‐hydroxylmethylpyrrolidine‐1‐propyne (abbreviated as R/S‐DPM ) we successfully prepared and single crystals were characterized of optically pure enantiomeric pair of atomically‐precise copper(I) clusters, [Cu 14 (R/S‐DPM) 8 ](PF 6 ) 6 (denoted as R/S‐Cu 14 ), which feature bright red luminescence and CPL with a high luminescence anisotropy factor ( g lum ). A dilute solution containing R/S‐Cu 14 was nonluminescent and CPL inactive at room temperature. Crystallization‐ and aggregation‐induced emission (CIE and AIE, respectively) contribute to the triggering of the CPL of R/S‐Cu 14 in the crystalline and aggregated states. Their AIE behavior and good biocompatibility indicated applications of these copper(I) clusters in cell imaging in HeLa and NG108‐15 cells." @default.
- W2970704366 created "2019-09-05" @default.
- W2970704366 creator A5005592293 @default.
- W2970704366 creator A5009219625 @default.
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- W2970704366 creator A5038347628 @default.
- W2970704366 creator A5067754189 @default.
- W2970704366 creator A5077844828 @default.
- W2970704366 date "2019-09-18" @default.
- W2970704366 modified "2023-10-18" @default.
- W2970704366 title "AIE Triggers the Circularly Polarized Luminescence of Atomically Precise Enantiomeric Copper(I) Alkynyl Clusters" @default.
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- W2970704366 doi "https://doi.org/10.1002/anie.201908909" @default.